ChemInform Abstract: IMINYL RADICALS IN GAS-PHASE SYNTHESIS. III. SYNTHESIS OF A TERMINALLY UNSATURATED NITRILE

1977 ◽  
Vol 8 (8) ◽  
pp. no-no
Author(s):  
W. D. CROW ◽  
H. MCNAB ◽  
J. M. PHILIP
Keyword(s):  
Gas Phase ◽  
Phase Synthesis ◽  
Gas Phase Synthesis ◽  
Unsaturated Nitrile

Iminyl radicals in gas-phase synthesis. III. Synthesis of a terminally unsaturated nitrile

1976 ◽  
Vol 29 (10) ◽  
pp. 2299 ◽  
Author(s):  
WD Crow ◽  
H McNab ◽  
JM Philip
Keyword(s):  
Gas Phase ◽  
Phase Synthesis ◽  
Gas Phase Synthesis ◽  
Unsaturated Nitrile

The previously reported generation of α- and ω-cyanoalkyl radicals has been substantially improved by the use of the oxime esters of cyclopentanone and cyclohexanone instead of the azines. Fragmentationof the α-cyanoalkyl radicals to acrylonitrile is still observed, but the efficiency of alkylation of the residue is considerably enhanced. A synthetic device is described for intercepting the first-formedω-cyanoalkyl radicals with the formation of terminally unsaturated nitriles. This involves pyrolysis of the 5,6-dihydro-4H-l,2-oxazin-6-ones. The preparation and pyrolysis of 4,4a,5,6-tetrahydro-3H-naphth[l,2-c][1,2]oxazin-3-one to 2-(but-3-eny1)benzonitrile is described.

ChemInform Abstract: Growth Mechanism of MoS2 Fullerene-Like Nanoparticles by Gas-Phase Synthesis.

ChemInform ◽  
2001 ◽  
Vol 32 (8) ◽  
pp. no-no
Author(s):  
A. Zak ◽  
Y. Feldman ◽  
V. Alperovich ◽  
R. Rosentsveig ◽  
R. Tenne
Keyword(s):  
Gas Phase ◽  
Growth Mechanism ◽  
Phase Synthesis ◽  
Gas Phase Synthesis

Substrate-Free Gas-Phase Synthesis of Graphene Sheets

Nano Letters ◽  
2008 ◽  
Vol 8 (7) ◽  
pp. 2012-2016 ◽  
Author(s):  
Albert Dato ◽  
Velimir Radmilovic ◽  
Zonghoon Lee ◽  
Jonathan Phillips ◽  
Michael Frenklach
Keyword(s):  
Gas Phase ◽  
Graphene Sheets ◽  
Phase Synthesis ◽  
Free Gas ◽  
Gas Phase Synthesis

Sixty Years after Wittig: Gas-Phase Synthesis of Lithium Trimethylammonium Methylide, [(CH3)3NCH2Li]+

2007 ◽  
Vol 119 (37) ◽  
pp. 7178-7181 ◽  
Author(s):  
Richard A. J. O'Hair ◽  
Tom Waters ◽  
Benjamin Cao
Keyword(s):  
Gas Phase ◽  
Phase Synthesis ◽  
Gas Phase Synthesis

Gas-phase synthesis of terbium and lutetium carboxylates

2008 ◽  
Vol 53 (12) ◽  
pp. 1878-1884 ◽  
Author(s):  
V. V. Utochnikova ◽  
O. V. Kotova ◽  
E. M. Shchukina ◽  
S. V. Eliseeva ◽  
N. P. Kuz’mina
Keyword(s):  
Gas Phase ◽  
Phase Synthesis ◽  
Gas Phase Synthesis

scholarly journals Gas-Phase Synthesis of Pyrazolo[3,4-b]pyridin-4-ones

Synthesis ◽  
2014 ◽  
Vol 47 (02) ◽  
pp. 242-248 ◽  
Author(s):  
Alison Hulme ◽  
Martha Mackay ◽  
Andrew Nortcliffe ◽  
Hamish McNab
Keyword(s):  
Gas Phase ◽  
Phase Synthesis ◽  
Gas Phase Synthesis
Sign in / Sign up

Export Citation Format

Share Document