ChemInform Abstract: REACTIONS OF TETRATHIONAPHTHALENE WITH TRANSITION METAL CARBONYLS. SYNTHESIS AND CHARACTERIZATION OF TWO NEW ORGANOMETALLIC SEMICONDUCTORS (C10H4S4NI)X AND (C10H4S4CO2(CO)2)X AND A TETRAIRON CLUSTER C10H4S4FE4(CO)12

1977 ◽  
Vol 8 (41) ◽  
pp. no-no
Author(s):  
B.-K. TEO ◽  
F. WUDL ◽  
J. J. HAUSER ◽  
A. KRUGER
Keyword(s):  
Transition Metal ◽  
Synthesis And Characterization ◽  
Metal Carbonyls ◽  
Transition Metal Carbonyls

The Characterization of Metal–Metal Bonds in Unsaturated Binuclear Homoleptic Transition Metal Carbonyls. The Compliance Matrix

2003 ◽  
Vol 217 (3) ◽  
pp. 189-204 ◽  
Author(s):  
Y. Xie ◽  
H. F. Schaefer
Keyword(s):  
Transition Metal ◽  
Metal Carbonyls ◽  
Constant Matrix ◽  
Compliance Matrix ◽  
Metal Bond ◽  
Metal Metal ◽  
Transition Metal Carbonyls ◽  
Inverse Force ◽  
Metal Bonds

AbstractThe compliance matrix (inverse force constant matrix) has been used to estimate metal–metal bond character for the homoleptic transition metal carbonyls Fe2(CO)n and Co2(CO)n. The results are often in agreement with other methods, but the compliance matrix provides a unique measure while other methods may be ambiguous. The more unsaturated compounds with fewer carbonyls have stronger metal–metal linkages, indicating a general, if not infallible, correlation between the diagonal compliance matrix element and the formal bond order, given by the 18-electron rule. It is found that the apparent metal–metal bond strength, as judged by the compliance matrix, is significantly enhanced by the bridging (as opposed to terminal) carbonyls. Thus one must only make precise comparisons between systems with the same numbers of bridging carbonyls.

Observation of Carbon–Carbon Coupling Reaction in Neutral Transition-Metal Carbonyls

2021 ◽  
Vol 12 (3) ◽  
pp. 1012-1017
Author(s):  
Chong Wang ◽  
Qinming Li ◽  
Xiangtao Kong ◽  
Huijun Zheng ◽  
Tiantong Wang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Coupling Reaction ◽  
Metal Carbonyls ◽  
Transition Metal Carbonyls

Synthesis and Characterization of a Rare Transition-Metal Oxothiostannate and Investigation of Its Photocatalytic Properties

2019 ◽  
Vol 58 (4) ◽  
pp. 2354-2362 ◽  
Author(s):  
Assma Benkada ◽  
Helge Reinsch ◽  
Michael Poschmann ◽  
Jan Krahmer ◽  
Nicole Pienack ◽  
...  
Keyword(s):  
Transition Metal ◽  
Photocatalytic Properties ◽  
Synthesis And Characterization
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