ChemInform Abstract: MASS SPECTRAL STUDIES. PART 120. FACILE IONIZATION INDUCED BY AMMONIUM SALTS: : MASS SPECTRA OF NONVOLATILE COMPOUNDS USING UNMODIFIED ELECTRON-IMPACT MASS SPECTROMETERS

1983 ◽  
Vol 14 (8) ◽  
Author(s):  
A. K. BOSE ◽  
B. N. PRAMANIK ◽  
P. L. BARTNER
1984 ◽  
Vol 62 (3) ◽  
pp. 554-560 ◽  
Author(s):  
D. S. Wulfman ◽  
James Roberts ◽  
Dennis K. Henderson ◽  
J. C. Romine ◽  
R. S. McDaniel Jr. ◽  
...  

Electron impact (EI) mass spectral studies of methyl diazoacetate, ethyl diazoacetate (1), methyl diazoacetoacetate (2), and dimethyl diazomalonate (3) indicate that loss of N2 is exceedingly difficult from the parent ion and was observed only with 3. Diazoacetylacetone exhibits an appreciable (M − 28)+. ExactMass and metastable transitions indicate fragmentation occurs in part via 1,2,3-oxadiazolium ion-radicals (6) or α-lactones (7) to furnish N2O and hyponitrite esters. (M − 28)+ from 1 results from loss of ethylene.


1975 ◽  
Vol 2 (2) ◽  
pp. 82-89 ◽  
Author(s):  
Roland M. De Sagher ◽  
André P. De Leenheer ◽  
Albert E. Claeys ◽  
Annie A. Cruyl

1988 ◽  
Vol 43 (12) ◽  
pp. 1151-1153 ◽  
Author(s):  
E. R. Rohwer ◽  
R.C. Beavis ◽  
C. Köster ◽  
J. Lindner ◽  
J. Grotemeyer ◽  
...  

A new ultra fast electron impact (El) ion source is pre­sented that produces a very short, high intensity electron beam, allowing medium resolution mass spectra to be re­corded without pulsing the ion accelerating voltages in a time-of-flight mass spectrometer (TOF-MS). The ion source requires minimum modification of any TOF-MS equipped with an electrostatic ion reflector and UV-laser. El-spectra are presented for comparison with literature spectra.


1981 ◽  
Vol 12 (29) ◽  
Author(s):  
M. A. ABOU-GHARBIA ◽  
D. T. TERWILLIGER ◽  
M. M. JOULLIE ◽  
R. M. SRIVASTAVA

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