ChemInform Abstract: MOLECULAR ORBITAL AND SPECTROSCOPIC STUDIES OF TRIPLE BONDS BETWEEN TRANSITION-METAL ATOMS. 2. THE D5-D5 RE2CL4(PR3)4 COMPOUNDS

1983 ◽  
Vol 14 (32) ◽  
Author(s):  
B. E. BURSTEN ◽  
F. A. COTTON ◽  
P. E. FANWICK ◽  
G. G. STANLEY ◽  
R. A. WALTON
Keyword(s):  
Transition Metal ◽  
Molecular Orbital ◽  
Spectroscopic Studies ◽  
Triple Bonds ◽  
Metal Atoms ◽  
Transition Metal Atoms

Molecular orbital and spectroscopic studies of triple bonds between transition-metal atoms. 2. The d5-d5 Re2Cl4(PR3)4 compounds

1983 ◽  
Vol 105 (9) ◽  
pp. 2606-2611 ◽  
Author(s):  
Bruce E. Bursten ◽  
F. Albert Cotton ◽  
Phillip E. Fanwick ◽  
George G. Stanley ◽  
Richard A. Walton
Keyword(s):  
Transition Metal ◽  
Molecular Orbital ◽  
Spectroscopic Studies ◽  
Triple Bonds ◽  
Metal Atoms ◽  
Transition Metal Atoms

Molecular orbital and spectroscopic studies of triple bonds between transition-metal atoms. 1. The d3-d3 Mo2L6 compounds (L = OR, NR2, CH2R)

1980 ◽  
Vol 102 (14) ◽  
pp. 4579-4588 ◽  
Author(s):  
Bruce E. Bursten ◽  
F. Albert Cotton ◽  
Jennifer C. Green ◽  
Elaine A. Seddon ◽  
George G. Stanley
Keyword(s):  
Transition Metal ◽  
Molecular Orbital ◽  
Spectroscopic Studies ◽  
Triple Bonds ◽  
Metal Atoms ◽  
Transition Metal Atoms

Review Lecture The use of free atoms of transition metals in chemical synthesis

1984 ◽  
Vol 396 (1810) ◽  
pp. 1-19 ◽  
Keyword(s):  
Transition Metal ◽  
Chemical Synthesis ◽  
Metal Cluster ◽  
Organometallic Compounds ◽  
Spectroscopic Studies ◽  
Cluster Compounds ◽  
Preparative Scale ◽  
Metal Atoms ◽  
Transition Metal Atoms ◽  
Atom Chemistry

Transition metal atoms were first used in chemical synthesis about 15 years ago and they now have an extensive chemistry. This review outlines the development of atom chemistry with emphasis on the fruitful partnership between spectroscopic studies and preparative scale studies of atom reactions. The preparation of organometallic compounds, coordination compounds, metal cluster compounds and catalysts from transition metal atoms are discussed, and the possibility of using atoms on an industrial scale is considered.

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