ChemInform Abstract: ONE-ELECTRON REDUCTION OF HALOTHANE (2-BROMO-2-CHLORO-1,1,1-TRIFLUOROETHANE) BY FREE RADICALS. RADIATION CHEMICAL MODEL SYSTEM FOR REDUCTIVE METABOLISM

1985 ◽  
Vol 16 (14) ◽  
Author(s):  
J. MOENIG ◽  
K.-D. ASMUS
Keyword(s):  
Free Radicals ◽  
Model System ◽  
Chemical Model ◽  
Radiation Chemical ◽  
Electron Reduction ◽  
Reductive Metabolism

scholarly journals Analysis of a chemical model system leading to chiral symmetry breaking: Implications for the evolution of homochirality

2013 ◽  
Vol 52 (1) ◽  
pp. 268-282 ◽  
Author(s):  
Brandy N. Morneau ◽  
Jaclyn M. Kubala ◽  
Carl Barratt ◽  
Pauline M. Schwartz
Keyword(s):  
Symmetry Breaking ◽  
Chiral Symmetry ◽  
Chiral Symmetry Breaking ◽  
Model System ◽  
Chemical Model

Reaction of Bromotrichloromethane Derived Free Radicals with Uracil in a Model System. Structures of Products Formed

1995 ◽  
Vol 23 (5) ◽  
pp. 431-442 ◽  
Author(s):  
Gerardo D. Castro ◽  
Christian J. Stamato ◽  
José A. Castro
Keyword(s):  
Free Radicals ◽  
Model System

One-electron reduction of tris(2,2'-bipyrimidine)ruthenium(2+) ion in aqueous solution: a photochemical, radiation chemical, and electrochemical study

1989 ◽  
Vol 93 (16) ◽  
pp. 6080-6088 ◽  
Author(s):  
Gilda Neshvad ◽  
Morton Z. Hoffman ◽  
Quinto G. Mulazzani ◽  
Margherita Venturi ◽  
Mauro Ciano ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Electrochemical Study ◽  
Radiation Chemical ◽  
Electron Reduction

Theoretical insights into the reductive metabolism of CCl4 by cytochrome P450 enzymes and the CCl4-dependent suicidal inactivation of P450

2014 ◽  
Vol 43 (39) ◽  
pp. 14833-14840 ◽  
Author(s):  
Xiao-Xi Li ◽  
Qing-Chuan Zheng ◽  
Yong Wang ◽  
Hong-Xing Zhang
Keyword(s):  
Cytochrome P450 ◽  
Reduction Product ◽  
Cytochrome P450 Enzymes ◽  
Electron Reduction ◽  
The One ◽  
Reductive Metabolism

The one-electron reduction product, ˙CCl3, irreversibly inactivates P450 via covalently binding to the meso-carbon, whereas the two successive one-electron reductions product, :CCl2, reversibly inhibits P450 by coordinating to iron.

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