ChemInform Abstract: Rearrangement of Ketones. Part 3. Kinetic Study and Intermediate Complexes in the Reaction of tert.-Butyl Phenyl Ketone (I) with Aluminum Chloride.

ChemInform ◽  
1989 ◽  
Vol 20 (9) ◽  
Author(s):  
M. C. FERNANDEZ-MONREAL ◽  
M. P. RUIZ ◽  
J. SAN-ROMAN
Keyword(s):  
Kinetic Study ◽  
Aluminum Chloride ◽  
Tert Butyl ◽  
Phenyl Ketone

A Photoelectron Investigation of Acyl Silanes: The Photoelectron Spectra of Trimethylsilyl Phenyl Ketone and Phenyl tert-Butyl Ketone

1975 ◽  
Vol 53 (16) ◽  
pp. 2446-2449 ◽  
Author(s):  
R. S. Brown
Keyword(s):  
Energy Level ◽  
Low Energy ◽  
Ionization Potentials ◽  
Photoelectron Spectra ◽  
Energy Level Diagram ◽  
Tert Butyl ◽  
Partial Energy ◽  
Phenyl Ketone ◽  
Butyl Ketone

The photoelectron spectra of trimethylsilyl phenyl ketone and phenyl tert-butyl ketone are presented and analyzed in terms of their constituent orbitals. A hyperconjugative interpretation for the low energy ionization potentials of the acyl silanes is postulated. A combination of p.e. spectroscopy and u.v. data are used to infer the level of the LUMO in these systems and to construct a partial energy level diagram.

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