ChemInform Abstract: Amino Acids and Peptides. Part 70. Optically Active α-Amino Acids, N-Boc-Amino Aldehydes, and α-Amino-β-hydroxy Acids from 2,3-Epoxy Alcohols.

ChemInform ◽  
1989 ◽  
Vol 20 (37) ◽  
Author(s):  
U. SCHMIDT ◽  
M. RESPONDEK ◽  
A. LIEBERKNECHT ◽  
J. WERNER ◽  
P. FISCHER
Keyword(s):  
Amino Acids ◽  
Optically Active ◽  
Hydroxy Acids ◽  
Amino Aldehydes ◽  
Epoxy Alcohols

ChemInform Abstract: Direct Organo-Catalytic Asymmetric α-Amination of Aldehydes - A Simple Approach to Optically Active α-Amino Aldehydes, α-Amino Alcohols, and α-Amino Acids.

ChemInform ◽  
2010 ◽  
Vol 33 (39) ◽  
pp. no-no
Author(s):  
Anders Boegevig ◽  
Karsten Juhl ◽  
Nagaswamy Kumaragurubaran ◽  
Wei Zhuang ◽  
Karl Anker Joergensen
Keyword(s):  
Amino Acids ◽  
Amino Alcohols ◽  
Simple Approach ◽  
Optically Active ◽  
Amino Aldehydes ◽  
Catalytic Asymmetric

Stereoselective reactions of chiral α-amino aldehydes

1988 ◽  
Vol 326 (1592) ◽  
pp. 573-578 ◽  
Keyword(s):  
Amino Acids ◽  
Molecular Modelling ◽  
Optically Active ◽  
Grignard Reagents ◽  
Amino Aldehydes ◽  
Lithium Enolates ◽  
Stereoselective Reactions ◽  
Chelating Reagents

Optically active α-amino acids can be converted into the corresponding doubly protected N,N-dibenzyl α-amino aldehydes. These react diastereoselectively with Grignard reagents, lithium enolates and Me 3 SiCN/ZnX 2 to provide the nonchelation-controlled adducts. Molecular modelling explains some of the results. The sense of stereoselectivity can be reversed if Lewis acidic chelating reagents are used. Undesired racemization does not occur.

Synthesis of Optically Active Phthaloyld-Aminooxy Acids froml-Amino Acids orl-Hydroxy Acids as Building Blocks for the Preparation of Aminooxy Peptides

2000 ◽  
Vol 65 (22) ◽  
pp. 7667-7675 ◽  
Author(s):  
Injae Shin ◽  
Mung-ryul Lee ◽  
Jiyong Lee ◽  
Mankil Jung ◽  
Weontae Lee ◽  
...  
Keyword(s):  
Amino Acids ◽  
Building Blocks ◽  
Optically Active ◽  
Hydroxy Acids

SOME DERIVATIVES OF OPTICALLY ACTIVE α-AMINO ALDEHYDES. AMINO ACIDS. X.1, 2

1953 ◽  
Vol 18 (3) ◽  
pp. 297-302 ◽  
Author(s):  
K. BALENOVIC ◽  
N. BREGANT ◽  
D. CERAR ◽  
D. FLES ◽  
I. JAMBRESIC
Keyword(s):  
Amino Acids ◽  
Optically Active ◽  
Amino Aldehydes ◽  
Derivatives Of

Chirality Sensing of Amines, Diamines, Amino Acids, Amino Alcohols, and α-Hydroxy Acids with a Single Probe

2013 ◽  
Vol 135 (48) ◽  
pp. 18052-18055 ◽  
Author(s):  
Keith W. Bentley ◽  
Yea G. Nam ◽  
Jaslynn M. Murphy ◽  
Christian Wolf
Keyword(s):  
Amino Acids ◽  
Amino Alcohols ◽  
Hydroxy Acids ◽  
Single Probe
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