ChemInform Abstract: Kinetics of Neutral Transition-Metal Atoms in the Gas Phase: Oxidation of Sc(a2D), Ti(a3F), and V(a4F) by NO, O2, and N2O.

ChemInform ◽  
1990 ◽  
Vol 21 (40) ◽  
Author(s):  
D. RITTER ◽  
J. C. WEISSHAAR
1964 ◽  
Vol 17 (5) ◽  
pp. 539
Author(s):  
JJ Batten

A study has been made of the effect of the surface-to-volume ratio of the reaction vessel and of coatings of various inorganic substances on the vessel walls on the gas-phase oxidation of methanol catalysed by nitric oxide. The results show that, whereas packing the vessel does not have a marked effect on the rate, the kinetics of the reaction are profoundly influenced by the nature of the surface. The results suggest that the methanol-oxidation chains are initiated at the surface by reaction between methanol and nitrogen dioxide, and that HO2 radicals play an important role in the subsequent chain reaction.


2006 ◽  
Vol 61 (11) ◽  
pp. 3564-3576 ◽  
Author(s):  
A. Aranzabal ◽  
J.A. González-Marcos ◽  
J.L. Ayastuy ◽  
J.R. González-Velasco

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