Kinetics of neutral transition-metal atoms in the gas phase: oxidation reactions of titanium (a3F) from 300 to 600 K

1993 ◽  
Vol 97 (30) ◽  
pp. 7942-7946 ◽  
Author(s):  
Mark L. Campbell ◽  
Roy E. McClean
Keyword(s):  
Transition Metal ◽  
Gas Phase ◽  
Oxidation Reactions ◽  
Metal Atoms ◽  
Transition Metal Atoms ◽  
Phase Oxidation ◽  
Gas Phase Oxidation ◽  
Kinetics Of

Effect of surface on the gas-phase oxidation of methanol catalysed by nitric oxide

1964 ◽  
Vol 17 (5) ◽  
pp. 539
Author(s):  
JJ Batten
Keyword(s):  
Nitric Oxide ◽  
Gas Phase ◽  
Marked Effect ◽  
Volume Ratio ◽  
Oxidation Of Methanol ◽  
Inorganic Substances ◽  
Phase Oxidation ◽  
Gas Phase Oxidation ◽  
Kinetics Of ◽  
Effect Of Surface

A study has been made of the effect of the surface-to-volume ratio of the reaction vessel and of coatings of various inorganic substances on the vessel walls on the gas-phase oxidation of methanol catalysed by nitric oxide. The results show that, whereas packing the vessel does not have a marked effect on the rate, the kinetics of the reaction are profoundly influenced by the nature of the surface. The results suggest that the methanol-oxidation chains are initiated at the surface by reaction between methanol and nitrogen dioxide, and that HO2 radicals play an important role in the subsequent chain reaction.

Kinetics of Pd/alumina catalysed 1,2-dichloroethane gas-phase oxidation

2006 ◽  
Vol 61 (11) ◽  
pp. 3564-3576 ◽  
Author(s):  
A. Aranzabal ◽  
J.A. González-Marcos ◽  
J.L. Ayastuy ◽  
J.R. González-Velasco
Keyword(s):  
Gas Phase ◽  
Phase Oxidation ◽  
Gas Phase Oxidation ◽  
Kinetics Of
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