ChemInform Abstract: Electrochemical Reduction of Carbon Dioxide at Various Metal Electrodes in Aqueous Potassium Hydrogen Carbonate Solution.

ChemInform ◽  
2010 ◽  
Vol 22 (1) ◽  
pp. no-no
Author(s):  
H. NODA ◽  
S. IKEDA ◽  
Y. ODA ◽  
K. IMAI ◽  
M. MAEDA ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Electrochemical Reduction ◽  
Carbonate Solution ◽  
Metal Electrodes ◽  
Potassium Hydrogen Carbonate ◽  
Hydrogen Carbonate ◽  
Potassium Hydrogen

Meisenheimer complex formation between 4,6-dinitrobenzofurazan 1-oxide and primary, secondary and tertiary aromatic amines

1984 ◽  
Vol 37 (5) ◽  
pp. 985 ◽  
Author(s):  
RW Read ◽  
RJ Spear ◽  
WP Norris
Keyword(s):  
Complex Formation ◽  
Aromatic Amine ◽  
Aromatic Amines ◽  
Carbonate Solution ◽  
Complexation Reaction ◽  
Amino Group ◽  
Aromatic Carbon ◽  
Potassium Hydrogen Carbonate ◽  
Hydrogen Carbonate ◽  
Potassium Hydrogen

The uncatalysed formation of stable 1 : 1 Meisenheimer complexes between primary, secondary and tertiary aromatic amines and 4,6-dinitrobenzofurazan 1-oxide has been investigated. The thermodynamic product is derived from reaction through the aromatic carbon para or, if this position is substituted, ortho to the amino group of the aromatic amine. The complexes are stable to acid but react in aqueous potassium hydrogen carbonate solution or with aliphatic or aromatic amines to give crystalline salts of the complexes. In the presence of 1,4-diazabicyclo[2.2.2]octane, aniline reacts with 4,6-dinitrobenzofurazan 1-oxide to give an unstable nitrogen-bonded complex which is slowly converted into the carbon-bonded complex. The scope of the complexation reaction has been investigated and some of the mechanistic implications of the results are discussed.

A 1:1 adduct of methyl α-D-glucopyranoside and potassium hydrogen carbonate

1969 ◽  
Vol 9 (1) ◽  
pp. 122-124 ◽  
Author(s):  
J.W. Berry ◽  
B.I. Mayall ◽  
J.T. Marvel ◽  
A.J. Deutschman
Keyword(s):  
Potassium Hydrogen Carbonate ◽  
Hydrogen Carbonate ◽  
Potassium Hydrogen

scholarly journals Understanding Selectivity for the Electrochemical Reduction of Carbon Dioxide to Formic Acid and Carbon Monoxide on Metal Electrodes

ACS Catalysis ◽  
2017 ◽  
Vol 7 (7) ◽  
pp. 4822-4827 ◽  
Author(s):  
Jeremy T. Feaster ◽  
Chuan Shi ◽  
Etosha R. Cave ◽  
Toru Hatsukade ◽  
David N. Abram ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Formic Acid ◽  
Electrochemical Reduction ◽  
Metal Electrodes

Electrochemical Reduction of Carbon Dioxide on Various Metal Electrodes in Low‐Temperature Aqueous  KHCO 3 Media

1990 ◽  
Vol 137 (6) ◽  
pp. 1772-1778 ◽  
Author(s):  
Masashi Azuma ◽  
Kazuhito Hashimoto ◽  
Masahiro Hiramoto ◽  
Masahiro Watanabe ◽  
Tadayoshi Sakata
Keyword(s):  
Carbon Dioxide ◽  
Low Temperature ◽  
Electrochemical Reduction ◽  
Metal Electrodes
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