ChemInform Abstract: A Simple One-Pot Synthesis of 2-Arylpropionic tert-Butyl Esters by Carbonylation.

ChemInform ◽  
2010 ◽  
Vol 23 (5) ◽  
pp. no-no
Author(s):  
C. S. N. PRASAD ◽  
S. R. ADAPA
1999 ◽  
Vol 23 (6) ◽  
pp. 368-369
Author(s):  
Issa Yavari ◽  
Abbas Ali Esmaili ◽  
Sakineh Asghari ◽  
Hamid Reza Bijanzadeh

The highly reactive 1:1 intermediate produced in the reaction between tert-butyl isocyanide and dialkyl acetylenedicarboxylates is trapped by dialkyl 2-bromomalonates to yield the title compounds in fairly high yields.


2021 ◽  
pp. 174751982098753
Author(s):  
Xiaofang Wu ◽  
Lei Zhou ◽  
Fangshao Li ◽  
Jing Xiao

A PCl3-mediated conversion of tert-butyl esters into esters and amides in one-pot under air is developed. This novel protocol is highlighted by the synthesis of skeletons of bioactive molecules and gram-scale reactions. Mechanistic studies revealed that this transformation involves the formation of an acid chloride in situ, which is followed by reactions with alcohols or amines to afford the desired products.


ChemInform ◽  
2010 ◽  
Vol 29 (1) ◽  
pp. no-no
Author(s):  
G. BARBARO ◽  
A. BATTAGLIA ◽  
A. GUERRINI ◽  
C. BERTUCCI
Keyword(s):  
One Pot ◽  

Synthesis ◽  
2019 ◽  
Vol 51 (22) ◽  
pp. 4215-4230 ◽  
Author(s):  
Adesh Kumar Singh ◽  
Rapelly Venkatesh ◽  
Jeyakumar Kandasamy

The palladium-catalyzed one-pot synthesis of 2,3-deoxy-3-keto aryl C-glycosides is achieved from glycals and anilines in the presence of tert-butyl nitrite and aqueous HBF4 under mild conditions. This one-pot method stereospecifically provides α- and β-aryl glycosides (≥19:1 by NMR) in good yields at room temperature. The configuration at the C-3 position in the glycal determines the anomeric selectivity (i.e., α or β) of the desired products.


ChemInform ◽  
2007 ◽  
Vol 38 (11) ◽  
Author(s):  
Masaharu Hashimoto ◽  
Satoshi Sakaguchi ◽  
Yasutaka Ishii
Keyword(s):  
One Pot ◽  

2009 ◽  
Vol 2009 (12) ◽  
pp. 1994-2002 ◽  
Author(s):  
Eszter Fördős ◽  
Róbert Tuba ◽  
László Párkányi ◽  
Tamás Kégl ◽  
Ferenc Ungváry

ChemInform ◽  
2005 ◽  
Vol 36 (20) ◽  
Author(s):  
Kazuhiro Kobayashi ◽  
Hironobu Umakoshi ◽  
Kazutaka Hayashi ◽  
Osamu Morikawa ◽  
Hisatoshi Konishi
Keyword(s):  
One Pot ◽  

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