ChemInform Abstract: Chlorine as a Poison of the Fused Iron Catalyst for Ammonia Synthesis.

ChemInform ◽  
2010 ◽  
Vol 27 (26) ◽  
pp. no-no
Author(s):  
W. ARABCZYK ◽  
U. NARKIEWICZ ◽  
D. MOSZYNSKI
2011 ◽  
Vol 400 (1-2) ◽  
pp. 48-53 ◽  
Author(s):  
Zofia Lendzion-Bieluń ◽  
Roman Jędrzejewski ◽  
Ewa Ekiert ◽  
Walerian Arabczyk

2008 ◽  
Vol 26 (5) ◽  
pp. 711-716 ◽  
Author(s):  
Xiujin YU ◽  
Bingyu LIN ◽  
Jianxin LIN ◽  
Rong WANG ◽  
Kemei WEI

2016 ◽  
Vol 18 (2) ◽  
pp. 78-83 ◽  
Author(s):  
Roman Jedrzejewski ◽  
Zofia Lendzion-Bieluń ◽  
Walerian Arabczyk

Abstract The iron catalyst precursor promoted with Al2O3, CaO, and Li2O was obtained applying the fusing method. Lithium oxide forms two phases in this iron catalyst: a chemical compound with iron oxide (Li2Fe3O4) and a solid solution with magnetite. The catalyst promoted with lithium oxide was not fully reduced at 773 K, while the catalyst containing potassium was easily reducible at the same conditions. After reduction at 873 K the activity of the catalyst promoted with lithium oxide was 41% higher per surface than the activity of the catalyst promoted with potassium oxide. The concentration of free active sites on the surface of the catalyst containing lithium oxide after full reduction was greater than the concentration of free active sites on the surface of the catalyst promoted with potassium oxide.


1996 ◽  
Vol 134 (2) ◽  
pp. 331-338 ◽  
Author(s):  
Walerian Arabczyk ◽  
Urszula Narkiewicz ◽  
Dariusz Moszyński

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