ChemInform Abstract: Kinetics and Mechanism of Oxidation of Benzyl Alcohol by Tetraethylammonium Chlorochromate: A New Chromium(VI) Oxidant.

ChemInform ◽  
2010 ◽  
Vol 28 (38) ◽  
pp. no-no
Author(s):  
A. PANDURANGAN ◽  
V. MURUGESAN
Keyword(s):  
Benzyl Alcohol ◽  
Kinetics And Mechanism ◽  
Chromium Vi ◽  
Oxidation Of Benzyl Alcohol ◽  
Mechanism Of Oxidation

scholarly journals Kinetic Evidence of a Common Mechanism in the Oxidation by Chromium(vi) Complexes: Oxidation of Benzyl Alcohol

2000 ◽  
Vol 2000 (3) ◽  
pp. 114-115 ◽  
Author(s):  
Chockalingam Karunakaran ◽  
Sadasivam Suresh
Keyword(s):  
Acetic Acid ◽  
Benzyl Alcohol ◽  
Perchloric Acid ◽  
Mineral Acid ◽  
Common Mechanism ◽  
Aqueous Acetic Acid ◽  
First Order ◽  
Chromium Vi ◽  
Oxidation Of Benzyl Alcohol

The oxidation of benzyl alcohol by dichromate and seven chromium(VI) complexes in aqueous acetic acid in the presence of perchloric acid is first order each in the oxidants, the alcohol and the mineral acid. The oxidation conforms to the isokinetic and Exner relationships and follows a common mechanism.

Kinetics and Mechanism of the Oxidation of Substituted Benzyl Alcohols by oxo(salen)manganese(V) complexes

2001 ◽  
Vol 2001 (5) ◽  
pp. 179-181 ◽  
Author(s):  
Vinita Kumbhat ◽  
Pradeep K. Sharma ◽  
Kalyan K. Banerji
Keyword(s):  
Hydrogen Atom ◽  
Benzyl Alcohol ◽  
Hydrogen Atom Transfer ◽  
Kinetics And Mechanism ◽  
Atom Transfer ◽  
Benzyl Alcohols ◽  
Hydride Ion ◽  
Oxidation Of Benzyl Alcohol

The oxidation of benzyl alcohol by oxo(salen)manganese (V) complexes proceeds via either a hydride-ion or a hydrogen-atom transfer from the alcohol to the manganese (V) complexes.

scholarly journals Kinetics and Mechanism of Slurry Phase Air Oxidation of Benzyl Alcohol over Zirconium Vanadate Catalyst

2020 ◽  
Vol 33 (1) ◽  
pp. 108-112
Author(s):  
Shweta Kanungo Joshi ◽  
Neena Sohani ◽  
Savita Khare ◽  
Rajendra Prasad
Keyword(s):  
Benzyl Alcohol ◽  
Kinetics And Mechanism ◽  
Air Oxidation ◽  
Redox Mechanism ◽  
Rate Law ◽  
Oxidation Of Benzyl Alcohol ◽  
Slurry Phase ◽  
Partial Pressures ◽  
Kinetics Of ◽  
Zirconium Vanadate

The kinetics of slurry phase air oxidation of benzyl alcohol to benzaldehyde over zirconium vanadate catalyst is reported in this study. Initial rates for the formation of product were determined by varying the partial pressures of the reactants. The data collected were found to satisfy a rate law: R = [(k1PBk2Po)/(k1PB + k2Po)]. The study suggests that reaction follows a Mars-Van Krevelen type of redox mechanism.

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