The First Non-Acid Catalytic Synthesis of tert-Butyl Ether from tert-Butyl Alcohol Using Ionic Liquid as Dehydrator.

ChemInform ◽  
2003 ◽  
Vol 34 (33) ◽  
Author(s):  
Feng Shi ◽  
Hai Xiong ◽  
Yanlong Gu ◽  
Shu Guo ◽  
Youquan Deng
Keyword(s):  
Ionic Liquid ◽  
Butyl Alcohol ◽  
Catalytic Synthesis ◽  
Butyl Ether ◽  
Tert Butyl ◽  
Tert Butyl Alcohol

Alkylation of phenol with tert-butyl alcohol catalyzed by ionic liquid-supported MCM-41 with different pore sizes

2018 ◽  
Vol 125 (1) ◽  
pp. 351-364 ◽  
Author(s):  
Tingshun Jiang ◽  
Yingjie Xie ◽  
Liming Dai ◽  
Yingying Li ◽  
Qian Zhao
Keyword(s):  
Ionic Liquid ◽  
Butyl Alcohol ◽  
Tert Butyl ◽  
Pore Sizes ◽  
Tert Butyl Alcohol ◽  
Mcm 41

Anaerobic biodegradation of methyl tert-butyl ether and tert-butyl alcohol in petrochemical wastewater

2012 ◽  
Vol 33 (16) ◽  
pp. 1937-1943 ◽  
Author(s):  
Mohammad Ghasemian ◽  
Mohammad Mehdi Amin ◽  
Eberhard Morgenroth ◽  
Neemat Jaafarzadeh
Keyword(s):  
Anaerobic Biodegradation ◽  
Butyl Alcohol ◽  
Methyl Tert Butyl Ether ◽  
Petrochemical Wastewater ◽  
Butyl Ether ◽  
Tert Butyl ◽  
Tert Butyl Alcohol

Methyl tert-butyl Ether and tert-butyl Alcohol Degradation by Fusarium solani

2005 ◽  
Vol 27 (22) ◽  
pp. 1797-1801 ◽  
Author(s):  
Miguel Magaña-Reyes ◽  
Marcia Morales ◽  
Sergio Revah
Keyword(s):  
Fusarium Solani ◽  
Butyl Alcohol ◽  
Methyl Tert Butyl Ether ◽  
Butyl Ether ◽  
Tert Butyl ◽  
Tert Butyl Alcohol

Alkylation of phenol/ tert ‑butyl alcohol on ionic liquid-immobilized SBA-15 with different pore sizes

2017 ◽  
Vol 80 ◽  
pp. 1031-1040 ◽  
Author(s):  
Tingshun Jiang ◽  
Minglan Fang ◽  
Yingying Li ◽  
Qian Zhao ◽  
Liming Dai
Keyword(s):  
Ionic Liquid ◽  
Butyl Alcohol ◽  
Tert Butyl ◽  
Pore Sizes ◽  
Tert Butyl Alcohol

The reaction between 2,2-di(4-nitrophenyl)1,1,1-trifluoroethane and tert-butoxide ion in tert-butyl alcohol solvent

1980 ◽  
Vol 58 (18) ◽  
pp. 1979-1982 ◽  
Author(s):  
Arnold Jarczewski ◽  
Kenneth T. Leffek
Keyword(s):  
Isotope Effects ◽  
Activation Parameters ◽  
Butyl Alcohol ◽  
Blue Colour ◽  
Butyl Ether ◽  
Tert Butyl ◽  
Kinetic Isotope ◽  
Tert Butyl Alcohol ◽  
Reaction Proceeds ◽  
Alcohol Solvent

The reaction between 2,2-di(4-nitrophenyl) 1,1,1-trifluoroethane and excess sodium tert-butoxide in tert-butyl alcohol takes place rapidly to yield first the olefin, by elimination of HF. This is followed by a slower addition of tert-butoxide to the olefin, which upon reaction with the solvent gives the tert-butyl ether as the final product. The blue anions involved in each of these reactions are observed.Rate constants, the primary deuterium kinetic isotope effects, and the activation parameters have been measured for the appearance of the initial blue colour and also for the formation of the olefin. It is concluded that the reaction proceeds by a reversible ElcB mechanism.

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