A New Lewis Acid System Palladium/TMSCl for Catalytic Aldol Condensation of Aldehydes with Ketones.

ChemInform ◽  
2004 ◽  
Vol 35 (45) ◽  
Author(s):  
Yulin Zhu ◽  
Yuanjiang Pan
ChemInform ◽  
2016 ◽  
Vol 47 (43) ◽  
Author(s):  
Chuan Du ◽  
Xiaoyu Wang ◽  
Shengfei Jin ◽  
Hui Shi ◽  
Yangming Li ◽  
...  
Keyword(s):  

2019 ◽  
Vol 55 (90) ◽  
pp. 13558-13561 ◽  
Author(s):  
Mukulesh Mondal ◽  
Manashi Panda ◽  
Nicholas W. Davis ◽  
Vickie McKee ◽  
Nessan J. Kerrigan

A dual Lewis acid system promotes the formal [3+2]-cycloaddition of enantioenriched donor–acceptor cyclopropanes with ketenes to afford cyclopentanones.


Synthesis ◽  
2017 ◽  
Vol 50 (06) ◽  
pp. 1350-1358 ◽  
Author(s):  
Cunde Wang ◽  
Xushun Qing ◽  
Ting Wang ◽  
Chenlu Dai ◽  
Zhenjie Su

An efficient iron/acetic acid system-mediated reductive cyclization reaction of substituted 2-aryl-3-nitro-2H-chromenes with substituted 2-nitrobenzaldehydes for the synthesis of 6-aryl-6H-chromeno[3,4-b]quinolines was developed. This reaction involves the sequential reduction, hydrolysis, aldol condensation, intramolecular addition, and the nucleophilic addition of substituted 2-aryl-3-nitro-2H-chromenes with substituted 2-nitrobenzaldehydes to give the corresponding 6H-chromeno[3,4-b]quinolines. This transformation provides a straightforward synthetic protocol for constructing substituted 6H-chromeno[3,4-b]quinoline derivatives. The structures of three typical products were confirmed by X-ray crystallography.


2008 ◽  
Vol 14 (33) ◽  
pp. 10201-10205 ◽  
Author(s):  
Shu-Yu Zhang ◽  
Yong-Qiang Tu ◽  
Chun-An Fan ◽  
Yi-Jun Jiang ◽  
Lei Shi ◽  
...  

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