First Catalytic Asymmetric Synthesis of ?-Amino-?-polyfluoroalkyl Ketones via Proline-Catalyzed Direct Asymmetric Carbon?Carbon Bond Formation Reaction of Polyfluoroalkylated Aldimines.

Kazumasa Funabiki; Masashi Nagamori; Sakiko Goushi; Masaki Matsui

doi:10.1002/chin.200505069

First Catalytic Asymmetric Synthesis of ?-Amino-?-polyfluoroalkyl Ketones via Proline-Catalyzed Direct Asymmetric Carbon?Carbon Bond Formation Reaction of Polyfluoroalkylated Aldimines.

ChemInform ◽

10.1002/chin.200505069 ◽

2005 ◽

Vol 36 (5) ◽

Author(s):

Kazumasa Funabiki ◽

Masashi Nagamori ◽

Sakiko Goushi ◽

Masaki Matsui

Keyword(s):

Asymmetric Synthesis ◽

Bond Formation ◽

Formation Reaction ◽

Carbon Bond ◽

Catalytic Asymmetric Synthesis ◽

Carbon Carbon Bond ◽

Catalytic Asymmetric ◽

Asymmetric Carbon

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First catalytic asymmetric synthesis of β-amino-β-polyfluoroalkyl ketones via proline-catalysed direct asymmetric carbon–carbon bond formation reaction of polyfluoroalkylated aldimines

Chemical Communications ◽

10.1039/b406000h ◽

2004 ◽

pp. 1928-1929 ◽

Cited By ~ 40

Author(s):

Kazumasa Funabiki ◽

Masashi Nagamori ◽

Sakiko Goushi ◽

Masaki Matsui

Keyword(s):

Asymmetric Synthesis ◽

Bond Formation ◽

Formation Reaction ◽

Carbon Bond ◽

Catalytic Asymmetric Synthesis ◽

Carbon Carbon Bond ◽

Catalytic Asymmetric ◽

Asymmetric Carbon

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Practical Asymmetric Synthesis of ?-Hydroxy-?-trifluoromethylated Ketones via the First Example of the in situ Generation of Trifluoroacetaldehyde and Its Successive Asymmetric Carbon?Carbon Bond Formation Reaction with Chiral Imines.

ChemInform ◽

10.1002/chin.200510024 ◽

2005 ◽

Vol 36 (10) ◽

Author(s):

Kazumasa Funabiki ◽

Wataru Hashimoto ◽

Masaki Matsui

Keyword(s):

Asymmetric Synthesis ◽

Bond Formation ◽

Formation Reaction ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

In Situ Generation ◽

Chiral Imines ◽

Asymmetric Carbon

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Catalytic asymmetric carbon-carbon bond formation: asymmetric synthesis of cis-decalin derivatives by palladium-catalyzed cyclization of prochiral alkenyl iodides

The Journal of Organic Chemistry ◽

10.1021/jo00281a007 ◽

1989 ◽

Vol 54 (20) ◽

pp. 4738-4739 ◽

Cited By ~ 160

Author(s):

Yoshihiro Sato ◽

Mikiko Sodeoka ◽

Masakatsu Shibasaki

Keyword(s):

Asymmetric Synthesis ◽

Bond Formation ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Palladium Catalyzed ◽

Catalytic Asymmetric ◽

Asymmetric Carbon

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Asymmetric synthesis of β-hydroxy-β-trifluoromethylated ketones via in situ generation of trifluoroacetaldehyde and its asymmetric carbon–carbon bond formation reaction with chiral imines in aqueous media

Journal of Fluorine Chemistry ◽

10.1016/j.jfluchem.2005.12.020 ◽

2006 ◽

Vol 127 (4-5) ◽

pp. 545-547 ◽

Cited By ~ 6

Author(s):

Kazumasa Funabiki ◽

Kazutoshi Hasegawa ◽

Yoshihiro Murase ◽

Hideyuki Nagaya ◽

Masaki Matsui

Keyword(s):

Asymmetric Synthesis ◽

Bond Formation ◽

Aqueous Media ◽

Formation Reaction ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

In Situ Generation ◽

Chiral Imines ◽

Asymmetric Carbon

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Asymmetric Synthesis of β-Hydroxy-β-trifluoromethylated Ketones via in situ Generation of Trifluoroacetaldehyde and Its Asymmetric Carbon—Carbon Bond Formation Reaction with Chiral Imines in Aqueous Media.

ChemInform ◽

10.1002/chin.200638084 ◽

2006 ◽

Vol 37 (38) ◽

Author(s):

Kazumasa Funabiki ◽

Kazutoshi Hasegawa ◽

Yoshihiro Murase ◽

Hideyuki Nagaya ◽

Masaki Matsui

Keyword(s):

Asymmetric Synthesis ◽

Bond Formation ◽

Aqueous Media ◽

Formation Reaction ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

In Situ Generation ◽

Chiral Imines ◽

Asymmetric Carbon

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Practical asymmetric synthesis of β-hydroxy-β-trifluoromethylated ketones via the first example of the in situ generation of trifluoro-acetaldehyde and its successive asymmetric carbon–carbon bond formation reaction with chiral imines

Chemical Communications ◽

10.1039/b408226e ◽

2004 ◽

pp. 2056-2057 ◽

Cited By ~ 12

Author(s):

Kazumasa Funabiki ◽

Wataru Hashimoto ◽

Masaki Matsui

Keyword(s):

Asymmetric Synthesis ◽

Bond Formation ◽

Formation Reaction ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

In Situ Generation ◽

Chiral Imines ◽

Asymmetric Carbon

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Catalytic asymmetric carbon–carbon bond formation using alkenes as alkylmetal equivalents

Nature Chemistry ◽

10.1038/nchem.1394 ◽

2012 ◽

Vol 4 (8) ◽

pp. 649-654 ◽

Cited By ~ 63

Author(s):

Rebecca M. Maksymowicz ◽

Philippe M. C. Roth ◽

Stephen P. Fletcher

Keyword(s):

Bond Formation ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Catalytic Asymmetric ◽

Asymmetric Carbon

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Chiral Thiophosphoramide and Thioamide Ligands in Catalytic Asymmetric Carbon-Carbon Bond-Formation Reactions

Synlett ◽

10.1055/s-2006-956486 ◽

2007 ◽

Vol 2007 (1) ◽

pp. 0019-0030 ◽

Cited By ~ 1

Author(s):

Min Shi ◽

Wen Zhang

Keyword(s):

Bond Formation ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Catalytic Asymmetric ◽

Asymmetric Carbon ◽

Bond Formation Reactions

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Enantioselective Total Synthesis of (-)-Strychnine: Development of a Highly Practical Catalytic Asymmetric Carbon?Carbon Bond Formation and Domino Cyclization.

ChemInform ◽

10.1002/chin.200505193 ◽

2005 ◽

Vol 36 (5) ◽

Author(s):

Takashi Ohshima ◽

Youjun Xu ◽

Ryo Takita ◽

Masakatsu Shibasaki

Keyword(s):

Total Synthesis ◽

Bond Formation ◽

Carbon Bond ◽

Enantioselective Total Synthesis ◽

Carbon Carbon Bond ◽

Catalytic Asymmetric ◽

Asymmetric Carbon

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Catalytic Asymmetric Synthesis of α-Amino Phosphonates Using Enantioselective Carbon−Carbon Bond-Forming Reactions

Journal of the American Chemical Society ◽

10.1021/ja048791i ◽

2004 ◽

Vol 126 (21) ◽

pp. 6558-6559 ◽

Cited By ~ 82

Author(s):

Shū Kobayashi ◽

Hiroshi Kiyohara ◽

Yoshitaka Nakamura ◽

Ryosuke Matsubara

Keyword(s):

Asymmetric Synthesis ◽

Carbon Bond ◽

Bond Forming ◽

Catalytic Asymmetric Synthesis ◽

Carbon Carbon Bond ◽

Bond Forming Reactions ◽

Catalytic Asymmetric ◽

Amino Phosphonates

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