Multianvil High-Pressure / High-Temperature Synthesis in Solid State Chemistry

ChemInform ◽  
2005 ◽  
Vol 36 (12) ◽  
Author(s):  
Hubert Huppertz
Author(s):  
Hubert Huppertz

AbstractDuring the last 60 years, new high pressure techniques and their exploitation have permitted the extension of attainable pressure/volume conditions, increased versatility of the apparatus, and hydrostaticity of the attained pressure in a remarkable way. In preparative solid state chemistry, high-pressure/high-temperature synthesis always played a minor role due to technical difficulties and costs. Piston-cylinder and Belt-apparatus both were limited to the working range up to 3 and 10 GPa, respectively. New technical developments, which allow synthesis up to 25 GPa, open up an enormous field of sample synthesis in solid state chemistry. In the following, a short overview on the most important developments in multianvil-techniques is given with respect to their applications for solid state chemistry under high-pressure conditions.


Author(s):  
Gunter Heymann ◽  
Elisabeth Selb ◽  
Toni Buttlar ◽  
Oliver Janka ◽  
Martina Tribus ◽  
...  

By high-pressure/high-temperature multianvil synthesis a new high-pressure (HP) phase of Co3TeO6 was obtained. The compound crystallizes in the acentric trigonal crystal system of the Ni3TeO6-type structure with space group R3...


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2004 ◽  
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pp. 2203-2206 ◽  
Author(s):  
V.M. Davidenko ◽  
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F.M. Shakhov ◽  
M.A. Yagovkina ◽  
V.A. Yashin ◽  
...  

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