Synthesis and Characterization of New Iridium Complexes with the (4S)-2-[2-(Diphenylphosphanyl)phenyl]-4-isopropyl-1,3-oxazoline Ligand that Catalyze Asymmetric Michael Reactions.

ChemInform ◽  
2005 ◽  
Vol 36 (37) ◽  
Author(s):  
Daniel Carmona ◽  
Joaquina Ferrer ◽  
Monica Lorenzo ◽  
Fernando J. Lahoz ◽  
Isabel T. Dobrinovitch ◽  
...  
2015 ◽  
Vol 44 (18) ◽  
pp. 8456-8466 ◽  
Author(s):  
John W. Facendola ◽  
Martin Seifrid ◽  
Jay Siegel ◽  
Peter I. Djurovich ◽  
Mark E. Thompson

Novel, emissive Pt(ii) and Ir(iii) complexes are the first to have measured rates of inversion of cyclometalated corannulene.


2012 ◽  
Vol 22 (42) ◽  
pp. 22721 ◽  
Author(s):  
Chul Young Kim ◽  
Dong-Gwang Ha ◽  
Hyun Hee Kang ◽  
Hui-Jun Yun ◽  
Soon-Ki Kwon ◽  
...  

Author(s):  
Erik Ekengard ◽  
Ida Bergare ◽  
Josefine Hansson ◽  
Isa Doverbratt ◽  
Magda Monari ◽  
...  

The synthesis and characterization of N-(2-((7-chloroquinolin-4-yl)amino)ethyl)pyrazine-2-carboxamide (<strong>L</strong>), an aminoquinoline – pyrazinamide hybrid, and the complexes (N-(2-((7-chloroquinolin-4-yl)amino)ethyl)pyrazine-2-carboxamide)(cyclopentadienyl) chlorido-rhodium or iridium hexafluorophosphate ([M(<strong>L</strong>)(Cp*)Cl] PF<sub>6</sub>; M = Rh, Ir) and the corresponding chlorido salts ([M(<strong>L</strong>)(Cp*) Cl]Cl; M = Rh, Ir) are described. The ligand and the hexafluorophosphate salts of the metal complexes have been evaluated for anti-plasmodial and anti-mycobacterial activity. The rhodium and the iridium complexes were significantly more active against <em>M. tuberculosis</em> than the free ligand. The crystallographically determined molecular structures of complexes (N-(2-((7-chloroquinolin-4-yl)amino)ethyl)pyrazine-2-carboxamide)(cyclopentadienyl)chlororhodium hexafluoro-phosphate and (N-(2-((7-chloroquinolin-4-yl)amino)ethyl)pyrazine-2-carboxamide)(cyclopentadienyl)chloro-iridium chloride are presented.


2007 ◽  
Vol 157 (21) ◽  
pp. 813-822 ◽  
Author(s):  
Yun Deng ◽  
Shu-Juan Liu ◽  
Qu-Li Fan ◽  
Chun Fang ◽  
Rui Zhu ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document