Photocatalytic Oxidation of Primary and Secondary Benzylic Alcohols to Carbonyl Compounds Catalyzed by H3PW12O40/SiO2 under an O2 Atmosphere.

ChemInform ◽  
2006 ◽  
Vol 37 (12) ◽  
Author(s):  
Saeid Farhadi ◽  
Mozhgan Afshari ◽  
Mansoureh Maleki ◽  
Zaynab Babazadeh
1987 ◽  
Vol 60 (11) ◽  
pp. 4143-4144 ◽  
Author(s):  
Takashi Morimoto ◽  
Masao Hirano ◽  
Hiroyuki Ashiya ◽  
Hidetaka Egashira ◽  
Xiumin Zhuang

2000 ◽  
Vol 131 (7) ◽  
pp. 799 ◽  
Author(s):  
Zorica Bugarcěić ◽  
Slobodan Novokmet ◽  
Zěeljko Senić ◽  
Zěivadin Bugarcěić

2005 ◽  
Vol 70 (5) ◽  
pp. 681-686 ◽  
Author(s):  
Zorica Bugarcic ◽  
Slobodan Novokmet ◽  
Vladan Kostic

The selective oxidation of benzylic alcohols to the corresponding carbonyl compounds is described. In alkaline solution, the oxidation reagent potassium tetrasodium diperiodatocuprate(III) dodecahydrate (KNa4[Cu(HIO6)2[12H2O] reacts with primary and secondary benzylic alcohols whereby good yields of the corresponding carbonyl compounds are obtained. The presented method provides for the selective oxidation of the benzylic hydroxyl group in compounds containing other types of alcoholic functional groups.


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