ChemInform Abstract: Formation of C—C Bonds via Catalytic Hydrogenation and Transfer Hydrogenation: Vinylation, Allylation, and Enolate Addition

ChemInform ◽  
2010 ◽  
Vol 41 (3) ◽  
Author(s):  
Ryan L. Patman ◽  
John F. Bower ◽  
In Su Kim ◽  
Michael J. Krische
Keyword(s):  
Catalytic Hydrogenation ◽  
Transfer Hydrogenation

scholarly journals Practical synthesis of enantiopure benzylamines by catalytic hydrogenation or transfer hydrogenation reactions in isopropanol using a Ru-pybox catalyst

2018 ◽  
Vol 5 (5) ◽  
pp. 841-849 ◽  
Author(s):  
E. de Julián ◽  
E. Menéndez-Pedregal ◽  
M. Claros ◽  
M. Vaquero ◽  
J. Díez ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Transfer Hydrogenation ◽  
Hydrogenation Reactions ◽  
Practical Synthesis ◽  
Very High

A Ru/Ph-pybox catalyst provides a very high enantioselectivity in the hydrogenation and transfer hydrogenation of N-aryl imines.

scholarly journals Simple NMR predictors of catalytic hydrogenation activity for [Rh(cod)Cl(NHC)] complexes featuring fluorinated NHC ligands

2019 ◽  
Vol 48 (25) ◽  
pp. 9317-9327 ◽  
Author(s):  
Mohamad Shazwan Shah Jamil ◽  
Sultan Alkaabi ◽  
Alan K. Brisdon
Keyword(s):  
Catalytic Hydrogenation ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Hydrogenation Activity ◽  
Nmr Parameters ◽  
Catalytic Transfer ◽  
Ligand Precursors

13C and 77Se NMR parameters for fluorinated NHC ligand precursors provide simple measures of the catalytic transfer-hydrogenation reactivity of the corresponding [Rh(cod)Cl(NHC)] complexes.

scholarly journals Mechanistic insight into the catalytic hydrogenation of nonactivated aldehydes with a Hantzsch ester in the presence of a series of organoboranes: NMR and DFT studies

RSC Advances ◽  
2019 ◽  
Vol 9 (18) ◽  
pp. 10201-10210 ◽  
Author(s):  
Go Hamasaka ◽  
Hiroaki Tsuji ◽  
Masahiro Ehara ◽  
Yasuhiro Uozumi
Keyword(s):  
Dft Calculations ◽  
Catalytic Hydrogenation ◽  
Transfer Hydrogenation ◽  
Dft Studies ◽  
Mechanistic Studies ◽  
Mechanistic Insight ◽  
Insight Into

Mechanistic studies on the organoborane-catalyzed transfer hydrogenation of nonactivated aldehydes with a Hantzsch ester as a synthetic NADPH analogue were performed by NMR experiments and DFT calculations.

Transfer hydrogenation of nitroarenes with hydrazine at near-room temperature catalysed by a MoO2 catalyst

2016 ◽  
Vol 18 (8) ◽  
pp. 2435-2442 ◽  
Author(s):  
Chaofeng Zhang ◽  
Jianmin Lu ◽  
Mingrun Li ◽  
Yehong Wang ◽  
Zhe Zhang ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Room Temperature ◽  
Hydrogen Transfer ◽  
Computational Study ◽  
Hydrogenation Reaction ◽  
Transfer Hydrogenation ◽  
Elementary Steps ◽  
Basic Properties

We present an experimental and computational study of the elementary steps of N2H4 hydrogen transfer on crystalline MoO2, and demonstrate its unique bifunctional metallic-basic properties in a catalytic hydrogenation reaction.

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