ChemInform Abstract: HgI2: A Novel Photocatalyst with High Performance in Degradation of Rhodamine B Dyes under Visible-Light Irradiation.

ChemInform ◽  
2015 ◽  
Vol 46 (50) ◽  
pp. no-no
Author(s):  
Jianting Tang ◽  
Datang Li ◽  
Zhaoxia Feng ◽  
Chengyun Long
RSC Advances ◽  
2014 ◽  
Vol 4 (110) ◽  
pp. 64747-64755 ◽  
Author(s):  
Xuefeng Xu ◽  
Man Wang ◽  
Yanyan Pei ◽  
Changchun Ai ◽  
Liangjie Yuan

The micro/nano-structure composite SiO2@Ag/AgCl was employed as a low cost photocatalyst for the degradation of RhB in aqueous solution under visible light irradiation, which exhibited excellent photocatalytic performance and stability.


2013 ◽  
Vol 17 (01n02) ◽  
pp. 135-141 ◽  
Author(s):  
Keishiro Tahara ◽  
Kumiko Mikuriya ◽  
Takahiro Masuko ◽  
Jun-ichi Kikuchi ◽  
Yoshio Hisaeda

The visible-light-driven dechlorination of 1,1-bis(4-chlorophenyl)-2,2,2-trichloroethane (DDT) was carried out in the presence of a hydrophobic vitamin B12 , heptamethyl cobyrinate perchlorate and Rhodamine B . DDT was successfully dechlorinated to form 1,1-bis(4-chlorophenyl)-2,2-dichloroethane (DDD) as the mono-dechlorinated product upon visible light irradiation with a tungsten lamp (λ > 440 nm). Upon prolonged visible light irradiation to DDT, DDMU (1-chloro-2,2-bis(4-chlorophenyl)ethylene), DDMS (1-chloro-2,2-bis(4-chlorophenyl)ethane) and DCS (trans-4,4′-dichlorostilbene) were obtained as the di- and tri-dechlorinated products. The use of the photostable organic sensitizer enabled prolonged photocatalysis via a noble-metal-free process. The vitamin B12 derivative was replaced by an imine/oxime-type cobalt complex although the cobalt complex system showed a lower catalytic activity than the B12 derivative system. The dechlorination mechanism in the B12 -Rhodamin B system was investigated by various methods such as UV-vis absorption and fluorescence quenching.


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