Visible‐light driven CO2 reduction to formate with electron mediated nicotinamide‐modified viologen in the system of water‐soluble zinc porphyrin and formate dehydrogenase

ChemNanoMat ◽  
2021 ◽  
Author(s):  
Akimitsu Miyaji ◽  
Yutaka Amao
RSC Advances ◽  
2020 ◽  
Vol 10 (69) ◽  
pp. 42354-42362
Author(s):  
Francesco Secundo ◽  
Yutaka Amao

Visible-light-driven CO2 reduction to formate with water-soluble zinc tetraphenylporphyrin tetrasulfonate, formate dehydrogenase from Candida boidinii and methylviologen in the presence of triethanolamine as an electron donor in an ionic liquid.


2021 ◽  
Author(s):  
Akimitsu Miyaji ◽  
Yutaka Amao

Visible-light driven CO2 reduction to formate with the system consisting of water-soluble zinc tetraphenylporphyrin tetrasulfonate (ZnTPPS), formate dehydrogenase from Candida boidinii (CbFDH) and 1-amino-1’-carbamoyl-4,4’- bipyridinium salt (ACBP) as an electron...


2018 ◽  
Vol 17 (1) ◽  
pp. 60-68 ◽  
Author(s):  
S. Ikeyama ◽  
Y. Amao

The effect of the functional ionic group of 4,4′-bipyridinium salt on the visible-light driven CO2 conversion to formic acid with the system consisting of zinc porphyrin and formate dehydrogenase was investigated.


2017 ◽  
Vol 1 (8) ◽  
pp. 1730-1733 ◽  
Author(s):  
S. Ikeyama ◽  
Y. Amao

An effective visible light-driven CO2 reduction to formic acid system was developed with zinc porphyrin, formate dehydrogenase and 1,1′-diaminoethyl-4,4′-bipyridinium salt.


2021 ◽  
Author(s):  
Yu Kita ◽  
Yutaka Amao

Lactate has received a great deal of attention as a raw material for biodegradable plastics. Lactate is synthesized by fermentative and chemical procedures. Using chemical procedure, lactate is synthesized industrially...


2021 ◽  
Author(s):  
Takayuki Katagiri ◽  
Yutaka Amao

We discovered the catalytic activity of Rh nanoparticles dispersed by polyvinylpyrrolidone (Rh-PVP) for NADH regeneration. Selective reduction of NAD+ to enzyme active NADH has successfully been achieved in the presence...


2016 ◽  
Vol 18 (1) ◽  
pp. 139-143 ◽  
Author(s):  
Akinobu Nakada ◽  
Kazuhide Koike ◽  
Kazuhiko Maeda ◽  
Osamu Ishitani

Even in an aqueous solution, a Ru(ii)–Re(i) supramolecular photocatalyst worked well for CO2 reduction. A water-soluble reductant BI(CO2−)H should be useful for evaluation of the real abilities of various photocatalytic systems.


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