Mechanochemically Activated, Calcium Oxide-Based, Magnesium Oxide-Stabilized Carbon Dioxide Sorbents

ChemSusChem ◽  
2016 ◽  
Vol 9 (17) ◽  
pp. 2380-2390 ◽  
Author(s):  
Alexey Kurlov ◽  
Marcin Broda ◽  
Davood Hosseini ◽  
Sharon J. Mitchell ◽  
Javier Pérez-Ramírez ◽  
...  
2016 ◽  
Vol 17 (1) ◽  
pp. 76-80
Author(s):  
O.M. Duda ◽  
I.J. Kostiv

The interaction of aqueous suspension of calcium chloride has been studied at different temperatures and at the duration of natural dolomite and solutions of sulfate acid and also carbon dioxide. Studied composition of formed products. Established that the reaction rate of magnesium oxide with acid or carbon dioxide is lower than calcium oxide. The conditions of obtaining of active magnesium with content ballast calcium carbonate and sulfate, which is connected to soluble calcium. For 1023 K temperature forms the most active magnesium oxide, increasing it to 1123 K, magnesium oxide is passivated and increasing the number of active calcium oxide. Soluble calcium compound completely pass into insoluble sulfates or carbonates by passing through a suspension of carbon dioxide or solution of sulfate acid neutralization. Thermo activated dolomite which containing active magnesium oxide and various forms of inert material can be used for obtaining magnesia binders.


2013 ◽  
Vol 723 ◽  
pp. 609-616
Author(s):  
Wei Chien Wang ◽  
Chih Chien Liu ◽  
Chau Lee

The furnace slag are the by-products of the steel industry, the main ingredients are the oxide of calcium, alumina and magnesium, and some silica. Slag used as concrete aggregate could cause the problem of the volume expansion of concrete. The expansion problem may be produced by ASR or free calcium oxide and magnesium oxide in slag. This research stabilizing the non-ASR reactive slag using steam treatment analyzes the effectiveness of steam treating technique inhibiting the expansive problem for slag used in concrete. And this paper also discusses the effect of the steam treating time on the performance of inhibiting the expansive problem.


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