Spontaneous Deposition of Prussian Blue on Reduced Graphene Oxide - Gold Nanoparticles Composites for the Fabrication of Electrochemical Biosensors

2014 ◽  
Vol 27 (1) ◽  
pp. 74-83 ◽  
Author(s):  
Xiaoyun Bai ◽  
Kwok-Keung Shiu
2020 ◽  
Vol 875 ◽  
pp. 114347
Author(s):  
Barbara Zakrzewska ◽  
Beata Dembinska ◽  
Sylwia Zoladek ◽  
Iwona A. Rutkowska ◽  
Jerzy Żak ◽  
...  

2012 ◽  
Vol 84 (9) ◽  
pp. 4057-4062 ◽  
Author(s):  
Kehung Chen ◽  
Ganhua Lu ◽  
Jingbo Chang ◽  
Shun Mao ◽  
Kehan Yu ◽  
...  

Nanomaterials ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 993 ◽  
Author(s):  
Baoyan Wu ◽  
Shihua Hou ◽  
Yongyong Xue ◽  
Zhan Chen

The study reports a facile and eco-friendly approach for nanomaterial synthesis and enzyme immobilization. A corresponding glucose biosensor was fabricated by immobilizing the gold nanoparticles (AuNPs) and glucose oxidase (GOD) multilayer films onto the polypyrrole (PPy)/reduced graphene oxide (RGO) modified glassy carbon electrode (GCE) via the electrodeposition and self-assembly. PPy and graphene oxide were first coated on the surface of a bare GCE by the electrodeposition. Then, AuNPs and GOD were alternately immobilized onto PPy-RGO/GCE electrode using the electrodeposition of AuNPs and self-assembly of GOD to obtain AuNPs-GOD multilayer films. The resulting PPy-RGO-(AuNPs-GOD)n/GCE biosensors were used to characterize and assess their electrocatalytic activity toward glucose using cyclic voltammetry and amperometry. The response current increased with the increased number of AuNPs-GOD layers, and the biosensor based on four layers of AuNPs-GOD showed the best performance. The PPy-RGO-(AuNPs-GOD)4/GCE electrode can detect glucose in a linear range from 0.2 mM to 8 mM with a good sensitivity of 0.89 μA/mM, and a detection limit of 5.6 μM (S/N = 3). This study presents a promising eco-friendly biosensor platform with advantages of electrodeposition and self-assembly, and would be helpful for the future design of more complex electrochemical detection systems.


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