Metal-Ion-Coordinating Properties of a Viral Inhibitor, a pyrophosphate analogue, and a herbicide metabolite, a glycinate analogue: The solution properties of the potentially five-membered chelates derived from phosphonoformic acid and (aminomethyl)phosphonic acid

1994 ◽  
Vol 77 (7) ◽  
pp. 1738-1756 ◽  
Author(s):  
Bin Song ◽  
Dong Chen ◽  
Matthias Bastian ◽  
Helmut Sigel ◽  
R. Bruce Martin
Keyword(s):  
Phosphonic Acid ◽  
Metal Ion ◽  
Solution Properties ◽  
Phosphonoformic Acid ◽  
Viral Inhibitor ◽  
Aminomethyl Phosphonic Acid

Determination of Glyphosate Herbicide and (Aminomethyl)phosphonic Acid in Natural Waters by Liquid Chromatography Using Pre-Column Fluorogenic Labeling with 9-Fluorenylmethyl Chloroformate

1986 ◽  
Vol 69 (3) ◽  
pp. 458-461 ◽  
Author(s):  
Carl J Miles ◽  
Louis R Wallace ◽  
H Anson Moye
Keyword(s):  
Liquid Chromatography ◽  
Phosphonic Acid ◽  
Natural Waters ◽  
Sample Pretreatment ◽  
Fluorescence Detector ◽  
Rotary Evaporation ◽  
Glyphosate Herbicide ◽  
And Storage ◽  
Aminomethyl Phosphonic Acid

Abstract An analytical method has been developed for determination of glyphosate herbicide and its major metabolite, (aminomethyl)phosphonic acid (AMFA), in natural waters. Sample pretreatment consisted of filtration, addition of phosphate buffer, concentration by rotary evaporation, and a final filtration before derivatization with 9-fluorenylmethyl chloroformate. The derivatives were separated by anion exchange liquid chromatography and measured with a fluorescence detector. Standard curves were linear over 3 orders of magnitude and minimal detectable quantities were 10 ng/mL for glyphosate and 5 ng/mL for AMPA. The 20-fold concentration factor realized in sample preparation corresponds to ppb method detection limits for glyphosate and AMPA in natural waters. Recovery and storage studies were performed and are discussed.

Evaluation of Titanium Dioxide as a Binding Phase for the Passive Sampling of Glyphosate and Aminomethyl Phosphonic Acid in an Aquatic Environment

2015 ◽  
Vol 87 (12) ◽  
pp. 6004-6009 ◽  
Author(s):  
Vincent Fauvelle ◽  
Tran-Thi Nhu-Trang ◽  
Thibaut Feret ◽  
Karine Madarassou ◽  
Jérôme Randon ◽  
...  
Keyword(s):  
Titanium Dioxide ◽  
Phosphonic Acid ◽  
Aquatic Environment ◽  
Passive Sampling ◽  
Binding Phase ◽  
Aminomethyl Phosphonic Acid

scholarly journals Monitoring of Glyphosate, Glufosinate-ammonium, and (Aminomethyl)phosphonic acid in ambient air of Provence-Alpes-Côte-d’Azur Region, France

2019 ◽  
Vol 204 ◽  
pp. 102-109 ◽  
Author(s):  
Sylvain Ravier ◽  
Marine Désert ◽  
Grégory Gille ◽  
Alexandre Armengaud ◽  
Henri Wortham ◽  
...  
Keyword(s):  
Phosphonic Acid ◽  
Ambient Air ◽  
Glufosinate Ammonium ◽  
Aminomethyl Phosphonic Acid
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