Rhodium‐Catalyzed Tandem Addition‐Cyclization of 1,5‐Enynes with Organoboronic Acids for the Synthesis of Alkylidene‐Cyclobutanes

Author(s):  
Hyeji Kim ◽  
Kyoungmin Choi ◽  
Dongseok Jang ◽  
Hyun-Suk Um ◽  
Yeehwan Kim ◽  
...  
Keyword(s):  
2018 ◽  
Author(s):  
Honggui Lv ◽  
Li-Jun Xiao ◽  
Dongbing Zhao ◽  
Qi-Lin Zhou

Herein, we realized the first linear-selective hydroarylation of unactivated alkenes and styrenes with organoboronic acids by introducing directing groupon alkenes. Our method is highly efficient and scalable, and provides a modular route to assemble structurally diverse alkylarenes, especially for γ-aryl butyric acid derivatives, which have been widely utilized as chemical feedstocks to access multiple marketed drugs, and biologically active compounds.<br>


Author(s):  
Tao Wang ◽  
Yanqing Wang ◽  
Kai Xu ◽  
Yuheng Zhang ◽  
Jiarui Guo ◽  
...  

2003 ◽  
Vol 68 (7) ◽  
pp. 2844-2852 ◽  
Author(s):  
Alan Nadin ◽  
José M. Sánchez López ◽  
Andrew P. Owens ◽  
Dean M. Howells ◽  
Adam C. Talbot ◽  
...  

2018 ◽  
Vol 9 (33) ◽  
pp. 6839-6843 ◽  
Author(s):  
Honggui Lv ◽  
Li-Jun Xiao ◽  
Dongbing Zhao ◽  
Qi-Lin Zhou

The first nickel(0)-catalyzed linear-selective hydroarylation of unactivated alkenes and styrenes with organoboronic acids are achieved under redox-neutral conditions.


Tetrahedron ◽  
2013 ◽  
Vol 69 (2) ◽  
pp. 537-541 ◽  
Author(s):  
Wen-Yong Han ◽  
Jian Zuo ◽  
Xiao-Mei Zhang ◽  
Wei-Cheng Yuan

2009 ◽  
Vol 74 (23) ◽  
pp. 9210-9213 ◽  
Author(s):  
Masami Kuriyama ◽  
Natsuki Ishiyama ◽  
Rumiko Shimazawa ◽  
Ryuichi Shirai ◽  
Osamu Onomura

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