scholarly journals Nickel(0)-catalyzed linear-selective hydroarylation of unactivated alkenes and styrenes with aryl boronic acids

2018 ◽  
Vol 9 (33) ◽  
pp. 6839-6843 ◽  
Author(s):  
Honggui Lv ◽  
Li-Jun Xiao ◽  
Dongbing Zhao ◽  
Qi-Lin Zhou
Keyword(s):  
Boronic Acids ◽  
Organoboronic Acids ◽  
Neutral Conditions

The first nickel(0)-catalyzed linear-selective hydroarylation of unactivated alkenes and styrenes with organoboronic acids are achieved under redox-neutral conditions.

Visible-light-induced deboronative alkylarylation of acrylamides with organoboronic acids

2019 ◽  
Vol 17 (27) ◽  
pp. 6612-6619 ◽  
Author(s):  
Xuezhi Li ◽  
Man-Yi Han ◽  
Bin Wang ◽  
Lei Wang ◽  
Min Wang
Keyword(s):  
Visible Light ◽  
Boronic Acids ◽  
Reaction Process ◽  
Tandem Reaction ◽  
Organoboronic Acids

A visible-light-induced deboronative alkylarylation of acrylamides with boronic acids was developed via a tandem reaction process.

A nickel-catalyzed anti-carbometallative cyclization of alkyne–azides with organoboronic acids: synthesis of 2,3-diarylquinolines

2018 ◽  
Vol 54 (7) ◽  
pp. 759-762 ◽  
Author(s):  
Gadi Ranjith Kumar ◽  
Ravi Kumar ◽  
Manda Rajesh ◽  
Maddi Sridhar Reddy
Keyword(s):  
Boronic Acids ◽  
Organoboronic Acids ◽  
Propargyl Alcohols

An anti-carbonickelative cyclization via reversible alkenylnickel E/Z isomerization of 2-azido phenyl propargyl alcohols with aryl boronic acids is achieved using Ni(acac)2 as the catalyst to access 2,3-diaryl quinolines.

An efficient desulfitative C–C cross coupling of fused thiazolidine-2-thione with boronic acids and boronic acid pinacol esters: formation of fused thiazoles

RSC Advances ◽  
2015 ◽  
Vol 5 (105) ◽  
pp. 86832-86839 ◽  
Author(s):  
Kandasamy Rajaguru ◽  
Arumugam Mariappan ◽  
Ramachandran Manjusri ◽  
Shanmugam Muthusubramanian ◽  
Nattamai Bhuvanesh
Keyword(s):  
Boronic Acid ◽  
Cross Coupling ◽  
Boronic Acids ◽  
Neutral Conditions

An efficient Pd(0)-catalyzed Cu(i)-mediated desulfitative C–C cross-coupling of benzo-fused thiazolidine-2-thione with boronic acids under neutral conditions and boronic acid pinacol esters under basic conditions has been demonstrated.

Synthesis of Ortho-Arylated and Alkenylated Benzamides by Palladium-Catalyzed Denitrogenative Cross-Coupling Reactions of 1,2,3-Benzotriazin-4(3H)‑Ones with Organoboronic Acids

2021 ◽  
Author(s):  
Hari Balakrishnan Madasamy ◽  
Kanagaraj Madasamy ◽  
Velayutham Sankar ◽  
Mahesh kumar Ravva ◽  
Mannathan Subramaniyan
Keyword(s):  
Cross Coupling ◽  
Boronic Acids ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Organoboronic Acids ◽  
Palladium Catalyzed

An efficient palladium-catalyzed denitrogenative Suzuki-Miyaura type cross-coupling of 1,2,3-benzotriazin-4(3H) ones with organoboronic acid is described. The reaction is compatible with various aryl and alkenyl boronic acids affording ortho-arylated and alkenylated...

A Self-Trapping, Bipolar Viologen Bromide Electrolyte for Aqueous Redox Flow Batteries

2020 ◽  
Author(s):  
wenda wu ◽  
Jian Luo ◽  
Fang Wang ◽  
Bing Yuan ◽  
Tianbiao Liu
Keyword(s):  
Redox Flow Battery ◽  
Capacity Retention ◽  
Redox Flow Batteries ◽  
Redox Electrolyte ◽  
Charge Process ◽  
Self Trapping ◽  
Flow Batteries ◽  
Total Capacity ◽  
Neutral Conditions ◽  
Low Solubility

Aqueous organic redox flow batteries (AORFBs) have become increasing attractive for scalable energy storage. However, it remains challenging to develop high voltage, powerful AORFBs because of the lack of catholytes with high redox potential. Herein, we report methyl viologen dibromide (<b>[MV]Br<sub>2</sub></b>) as a facile self-trapping, bipolar redox electrolyte material for pH neutral redox flow battery applications. The formation of the <b>[MV](Br<sub>3</sub>)<sub>2</sub></b> complex was computationally predicted and experimentally confirmed. The low solubility <b>[MV](Br<sub>3</sub>)<sub>2</sub></b> complex in the catholyte during the battery charge process not only mitigates the crossover of charged tribromide species (Br<sub>3</sub><sup>-</sup>) and addresses the toxicity concern of volatile bromine simultaneously. A 1.53 V bipolar MV/Br AORFB delivered outstanding battery performance at pH neutral conditions, specifically, 100% total capacity retention, 133 mW/cm<sup>2</sup> power density, and 60% energy efficiency at 40 mA/cm<sup>2</sup>.

A Mild and Simple Method for Making MIDA Boronates

2020 ◽  
Author(s):  
Aidan Kelly ◽  
Peng-Jui (Ruby) Chen ◽  
Jenna Klubnick ◽  
Daniel J. Blair ◽  
Martin D. Burke
Keyword(s):  
Organic Synthesis ◽  
Boronic Acids ◽  
Simple Method ◽  
Direct Preparation ◽  
Synthesis Procedure ◽  
Harsh Conditions

<div> <div> <div> <p>Existing methods for making MIDA boronates require harsh conditions and complex procedures to achieve dehydration. Here we disclose that a pre-dried form of MIDA, MIDA anhydride, acts as both a source of the MIDA ligand and an in situ desiccant to enable a mild and simple MIDA boronate synthesis procedure. This method expands the range of sensitive boronic acids that can be converted into their MIDA boronate counterparts. Further utilizing unique properties of MIDA boronates, we have developed a MIDA Boronate Maker Kit which enables the direct preparation and purification of MIDA boronates from boronic acids using only heating and centrifuge equipment that is widely available in labs that do not specialize in organic synthesis. </p> </div> </div> </div>

Ni(0)-Catalyzed α-Allylic Alkylation of Regular Ketones with 1,3-Dienes under pH and Redox-neutral Conditions

2019 ◽  
Author(s):  
Tiantian Chen ◽  
Yang Yang ◽  
Liyu Xie ◽  
Haijian Yang ◽  
Guangbin Dong ◽  
...  
Keyword(s):  
Oxidative Addition ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Dual Role ◽  
Allylic Alkylation ◽  
Cross Coupling Reaction ◽  
Neutral Conditions

<p>We report a Ni(0)-catalyzed cross coupling reaction between simple ketones and 1,3-dienes. A variety of a-allylic alkylation products were formed in an 1,2-addition manner with excellent regioselectivity. Water was found to significantly accelerate this transformation. A HO-Ni-H species generated from oxidative addition of Ni(0) to H<sub>2</sub>O is proposed to play a “dual role” in activating both the ketone and the diene substrate.</p>

Nickel(0)-Catalyzed Linear-Selective Hydroarylation of Unactivated Alkenes and Styrenes with Arylboron Acids

2018 ◽  
Author(s):  
Honggui Lv ◽  
Li-Jun Xiao ◽  
Dongbing Zhao ◽  
Qi-Lin Zhou
Keyword(s):  
Butyric Acid ◽  
Biologically Active Compounds ◽  
Biologically Active ◽  
Active Compounds ◽  
Highly Efficient ◽  
Organoboronic Acids

Herein, we realized the first linear-selective hydroarylation of unactivated alkenes and styrenes with organoboronic acids by introducing directing groupon alkenes. Our method is highly efficient and scalable, and provides a modular route to assemble structurally diverse alkylarenes, especially for γ-aryl butyric acid derivatives, which have been widely utilized as chemical feedstocks to access multiple marketed drugs, and biologically active compounds.<br>

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