Fractography of poly(methyl methacrylates)

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D. T. Turner
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Vol 26 (23) ◽  
pp. 6220-6225 ◽  
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Eli M. Pearce ◽  
T. K. Kwei
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A. V. Yakimanskii ◽  
O. V. Nazarova ◽  
E. Yu. Melenevskaya ◽  
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Polymer ◽  
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Vol 24 (7) ◽  
pp. 1487-1495 ◽  
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A. J. Schouten

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Vol 18 (1) ◽  
pp. 143-154 ◽  
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D. T. Turner
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1990 ◽  
Vol 34 (1) ◽  
pp. 213-226 ◽  
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Jiří Spêváček ◽  
Jaroslav Straka ◽  
Jan Štokr

e-Polymers ◽  
2009 ◽  
Vol 9 (1) ◽  
Author(s):  
Ekaterina R. Gasilova ◽  
Olga G. Zakharova ◽  
Sergey D. Zaitsev ◽  
Yury D. Semchikov

AbstractSelf-assembly of poly(methyl methacrylates) end-capped with -Ge(C6F5)3 groups (PMMA-F) has been studied in a selective solvent (acetone) by means of photon correlation spectroscopy and static light scattering. PMMA-F’s of different molecular weights (MW), were obtained by radical polymerization in the presence of a chain transfer agent, HGe(C6F5)3. At MW>130 000 conformational and hydrodynamic properties of PMMA-F’s is shown to be the same as of PMMA. At MW less than130 000 an aggregation starts: additional fraction of large scatterers appears in PCS. Large aggregates of Rh=200 - 300 nm are likely to be formed by bridged micellar clusters. Presence of large aggregates indicates a super strong segregation limit predicted in the work of Semenov et al.


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