Reaction kinetics of a series of alkenes with ClO and BrO radicals: A theoretical study

2020 ◽  
Vol 53 (2) ◽  
pp. 250-264
Author(s):  
Parth Gupta ◽  
B. Rajakumar
Keyword(s):  
Reaction Kinetics ◽  
Theoretical Study ◽  
Kinetics Of

Experimental and Theoretical Study of the Reaction Kinetics of 2,5-Dimethylterephthalonitrile Bromination Compared to 1,4-Dimethylbenzene Bromination

Synthesis ◽  
2018 ◽  
Vol 50 (06) ◽  
pp. 1259-1263
Author(s):  
Cibeli Villalba ◽  
Thiago de C Rozada ◽  
Fábio dos Santos ◽  
Leandro Scorsin ◽  
Jarem Garcia ◽  
...  
Keyword(s):  
Reaction Kinetics ◽  
Theoretical Study ◽  
Theoretical Studies ◽  
Bromination Reaction ◽  
Kinetics Of ◽  
Experimental And Theoretical Studies

Experimental and theoretical studies showed the differences observed in the benzylic tetrabromination reactions in 2,5-dimethylterephthalonitrile compared to 1,4-dimethylbenzene. It was observed that the compound containing the nitrile substituent underwent a slower bromination reaction, with the formation of four intermediate compounds, while for the compound without substituents, the reaction was faster and only two intermediate compounds were observed.

Theoretical Study of the Reaction Kinetics of Atomic Bromine with Tetrahydropyran

2015 ◽  
Vol 119 (6) ◽  
pp. 933-942 ◽  
Author(s):  
Binod Raj Giri ◽  
John M. H. Lo ◽  
John M. Roscoe ◽  
Awad B. S. Alquaity ◽  
Aamir Farooq
Keyword(s):  
Reaction Kinetics ◽  
Theoretical Study ◽  
Kinetics Of

Impact Of Synthesis Route on the Water Oxidation Kinetics of Hematite Photoanodes

2020 ◽  
Author(s):  
Camilo A. Mesa ◽  
Ludmilla Steier ◽  
Benjamin Moss ◽  
Laia Francàs ◽  
James E. Thorne ◽  
...  
Keyword(s):  
Oxygen Vacancy ◽  
Reaction Kinetics ◽  
Water Oxidation ◽  
Oxidation Kinetics ◽  
Oxidation Reaction ◽  
Charge Accumulation ◽  
Optical Signals ◽  
Current Voltage ◽  
Voltage Performance ◽  
Kinetics Of

<p><i>Operando</i> spectroelectrochemical analysis is used to determine the water oxidation reaction kinetics for hematite photoanodes prepared using four different synthetic procedures. Whilst these photoanodes exhibit very different current / voltage performance, their underlying water oxidation kinetics are found to be almost invariant. Lower photoanode performance was found to correlate with the observation of optical signals indicative of charge accumulation in mid-gap oxygen vacancy states, indicating these states do not contribute directly to water oxidation.</p>

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