Products of the gas-phase reaction of methyltert-butyl ether with the OH radical in the presence of NOx

1991 ◽  
Vol 23 (11) ◽  
pp. 1003-1015 ◽  
Author(s):  
Ernesto C. Tuazon ◽  
William P. L. Carter ◽  
Sara M. Aschmann ◽  
Roger Atkinson
Keyword(s):  
Gas Phase ◽  
Phase Reaction ◽  
Oh Radical ◽  
Butyl Ether ◽  
Gas Phase Reaction

ChemInform Abstract: Products of the Gas-Phase Reaction of Methyl tert-Butyl Ether with the OH Radical in the Presence of NOx

ChemInform ◽  
2010 ◽  
Vol 23 (5) ◽  
pp. no-no
Author(s):  
E. C. TUAZON ◽  
W. P. L. CARTER ◽  
S. M. ASCHMANN ◽  
R. ATKINSON
Keyword(s):  
Gas Phase ◽  
Methyl Tert Butyl Ether ◽  
Phase Reaction ◽  
Oh Radical ◽  
Butyl Ether ◽  
Gas Phase Reaction ◽  
Tert Butyl

Temperature Dependent Rate Coefficients for the Gas-Phase Reaction of the OH Radical with Linear (L2, L3) and Cyclic (D3, D4) Permethylsiloxanes

2018 ◽  
Vol 122 (17) ◽  
pp. 4252-4264 ◽  
Author(s):  
François Bernard ◽  
Dimitrios K. Papanastasiou ◽  
Vassileios C. Papadimitriou ◽  
James B. Burkholder
Keyword(s):  
Gas Phase ◽  
Rate Coefficients ◽  
Phase Reaction ◽  
Oh Radical ◽  
Temperature Dependent ◽  
Gas Phase Reaction ◽  
Dependent Rate

scholarly journals Rate coefficients for the gas-phase reaction of OH with <i>Z</i>-3-hexen-1-ol, 1-penten-3-ol, <i>E</i>-2-penten-1-ol, and <i>E</i>-2-hexen-1-ol between 243 and 404 K

2011 ◽  
Vol 11 (1) ◽  
pp. 2377-2405 ◽  
Author(s):  
M. E. Davis ◽  
J. B. Burkholder
Keyword(s):  
Gas Phase ◽  
Negative Temperature ◽  
Rate Coefficients ◽  
Oh Radicals ◽  
Phase Reaction ◽  
Oh Radical ◽  
Gas Phase Reaction ◽  
First Order ◽  
Unsaturated Alcohols ◽  
Temperature Dependences

Abstract. Rate coefficients, k, for the gas-phase reaction of the OH radical with (Z)-3-hexen-1-ol ((Z)-CH3CH2CH=CHCH2CH2OH). (k1), 1-penten-3-ol (CH3CH2CH(OH)CH=CH2) (k2), (E)-2-penten-1-ol ((E)-CH3CH2CH=CHCH2OH) (k3), and (E)-2-hexen-1-ol ((E)-CH3CH2CH2CH=CHCH2OH) (k4), unsaturated alcohols that are emitted into the atmosphere following vegetation wounding, are reported. Rate coefficients were measured under pseudo-first-order conditions in OH over the temperature range 243–404 K at pressures between 20 and 100 Torr (He) using pulsed laser photolysis (PLP) to produce OH radicals and laser induced fluorescence (LIF) to monitor the OH temporal profile. The obtained rate coefficients were independent of pressure with negative temperature dependences that are well described by the Arrhenius expressions k1(T) = (1.3 ± 0.1) × 10−11 exp[(580 ± 10)/T]; k1(297K) = (1.06 ± 0.12) × 10−10 k2(T) = (6.8 ± 0.7) × 10−12 exp[(690 ± 20)/T]; k2(297K) = (7.12 ± 0.73) × 10−11 k3(T) = (6.8 ± 0.8) × 10−12 exp[(680 ± 20)/T]; k3(297K) = (6.76 ± 0.70) × 10−11 k4(T) = (5.4 ± 0.6) × 10−12 exp[(690 ± 20)/T]; k4(297K) = (6.15 ± 0.75) × 10−11 (in units of cm3 molecule−1 s−1). The quoted uncertainties are at the 2σ (95% confidence) level and include estimated systematic errors. The rate coefficients obtained in this study are compared with literature values where possible.

Formation of 3-Methylfuran from the gas-phase reaction of OH radicals with isoprene and the rate constant for its reaction with the OH radical

1989 ◽  
Vol 21 (7) ◽  
pp. 593-604 ◽  
Author(s):  
Roger Atkinson ◽  
Sara M. Aschmann ◽  
Ernesto C. Tuazon ◽  
Janet Arey ◽  
Barbara Zielinska
Keyword(s):  
Gas Phase ◽  
Rate Constant ◽  
Oh Radicals ◽  
Phase Reaction ◽  
Oh Radical ◽  
Gas Phase Reaction
Sign in / Sign up

Export Citation Format

Share Document