The Effect of SEBS/Halloysite Masterbatch Obtained in Different Extrusion Conditions on the Properties of Hybrid Polypropylene/Glass Fiber Composites for Auto Parts

Masterbatches from a linear poly[styrene-b-(ethylene-co-butylene)-b-styrene] (SEBS) and halloysite nanotubes (HNT-QM) were obtained in different conditions of temperature and shear using two co-rotating twin-screw extruders. The influence of screw configuration and melt processing conditions on the morpho-structural, thermal and mechanical properties of masterbatches at macro and nanoscale was studied. A good dispersion of halloysite nanotubes and better thermal stability and tensile and nanomechanical properties were obtained at a lower temperature profile and higher screw speed. The effect of masterbatches, the best and worst alternatives, on the properties of a polypropylene (PP)–glass fiber (GF) composite was also evaluated. Double hardness, tensile strength and modulus and four times higher impact strength were obtained for PP/GF composites containing masterbatches compared to pristine PP. However, the masterbatch with the best properties led further to enhanced mechanical properties of the PP/GF composite. A clear difference between the effects of the two masterbatches was obtained by nanoindentation and nanoscratch tests. These analyses proved to be useful for the design of polymer composites for automotive parts, such as bumpers or door panels. This study demonstrated that setting-up the correct processing conditions is very important to obtain the desired properties for automotive applications.

MICROSTRUCTURAL CORRELATIONS IN SHORT-ALIGNED GLASS FIBER COMPOSITES

Research shows that in unidirectional composites, fiber breaks and clusters of fiber breaks play a role in the failure onset of the composites [1]. So far, we know no attempts to the date have been made to analyze the fiber break development in short-aligned fiber composites, specifically using E-glass HYBON 2026. O[1]ur challenge is to determine whether there is a similar behavior in aligned short composites and its relationship with the microstructural parameter of fiber orientation distribution. This is important as it is measurable parameter to add value to recycled fiber composites. The more aligned the composite the higher mechanical properties and the higher the added value for recycling. We focused on using synchrotron x-ray computed tomography while performing hold-at-displacement scans to evaluate the fiber microstructure. We found the fiber breaks do not have the same orientation distribution as the non-broken fibers.

Carbon Nanotube Reinforced Poly(ε-caprolactone)/Epoxy Blends for Superior Mechanical and Self-Sensing Performance in Multiscale Glass Fiber Composites

In this paper, a novel carbon nanotube (CNT) polycaprolactone (PCL), epoxy, and glass fiber (GF) composite is reported. Here, the nanoreinforced composites show a flexural strength increase of around 30%, whereas the interlaminar shear strength increases by 10–15% in comparison to unenhanced samples. This occurs because the addition of the CNTs induces a better PCL/epoxy/GF interaction. Furthermore, the nanoparticles also give novel functionalities to the multiscale composite, such as strain and damage monitoring. Here, the electrical response of the tensile- and compressive-subjected faces was simultaneously measured during flexural tests as well as the transverse conductivity in interlaminar tests, showing an exceptional capability for damage detection. Moreover, it was observed that the electrical sensitivity increases with PCL content due to a higher efficiency of the dispersion process that promotes the creation of a more uniform electrical network.