Preparation and characterization of microencapsulated LDHs with melamine-formaldehyde resin and its flame retardant application in epoxy resin

2018 ◽  
Vol 29 (7) ◽  
pp. 2147-2160 ◽  
Author(s):  
Ping Zhu ◽  
Zhongji Gu ◽  
Shu Hong ◽  
Hailan Lian
2006 ◽  
Vol 11 (4) ◽  
pp. 332-336 ◽  
Author(s):  
Jun-Seok Hwang ◽  
Jin-Nam Kim ◽  
Young-Jung Wee ◽  
Jong-Sun Yun ◽  
Hong-Gi Jang ◽  
...  

2020 ◽  
Vol 1003 ◽  
pp. 205-212
Author(s):  
Fu Long Zhou ◽  
Hong Zhi Wu ◽  
Ming Mei Sun ◽  
Xin Zhu ◽  
Lin Sheng Tang

A new triazine charring agent, melamine formaldehyde resin modified with pentaerythritol (named as MF-MPOL), was synthesized through hydroxymethylation, condensation and etherification by using melamine, paraformaldehyde and pentaerythritol as raw materials, and characterized by solid-state 13C NMR and FT-IR. The intumescent flame retardant (IFR) consisting of MF-MPOL with ammonium polyphosphate has good flame retardancy in polypropylene (PP). The analysis of the residues obtained in cone calorimetry test showed that the IFR played a role of flame retardancy mainly in condensed phase. In other words, the porous and dense - continuous intumescent char layer formed during the burning process results in flame retardant effect by insulation of heat, oxygen and preventing the underlying PP from degradation and volatilization of pyrolytic products.


2014 ◽  
Vol 628 ◽  
pp. 24-27
Author(s):  
Jun Xia Liu ◽  
Lei Zhou ◽  
Qi Bin Jiang ◽  
Jin Yang ◽  
Jian Jun Xie

The effects of mole ratio of formaldehyde and melamine (F/M), solution pH, reaction temperature and time on the foaming melamine-formaldehyde resin (MF resin) with caprolactam as modifier were investigated by orthogonal experiment design where the solid content and the viscosity of the resin, the density and the size uniformity of the foam resin were used as performance evaluation parameters. The results had shown that the optimal conditions for preparing the foaming MF resin were F/M= 3.25, pH=8.0, T=90°C, t=45min. The MF resin prepared under the optimal conditions could be foamed well and its storage time was prolonged to 16 days. The structure and thermal properties of MF resin under the optimal conditions were investigated.


2012 ◽  
Vol 51 (10) ◽  
pp. 1976-1990 ◽  
Author(s):  
Kongying Zhu ◽  
Hengzhi Qi ◽  
Shuang Wang ◽  
Jianwei Zhou ◽  
Yunhui Zhao ◽  
...  

2007 ◽  
Vol 12 (4) ◽  
pp. 301-314 ◽  
Author(s):  
Manuela Leidl ◽  
Werner F. Huber ◽  
Clemens Schwarzinger ◽  
Andreas Endesfelder

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