Structure and reactivity in the hydrolyses of aliphatic carboxylic acid esters and chlorides

2007 ◽  
Vol 20 (3) ◽  
pp. 180-189 ◽  
Author(s):  
Andrew C. Regan ◽  
C. Ian F. Watt
Keyword(s):  
Carboxylic Acid ◽  
Aliphatic Carboxylic Acid ◽  
Acid Esters

Ketones from Nickel-Catalyzed Decarboxylative, Non-Symmetric Cross-Electrophile Coupling of Carboxylic Acid Esters

2019 ◽  
Author(s):  
Jiang Wang ◽  
Brian P. Cary ◽  
Peyton Beyer ◽  
Samuel H. Gellman ◽  
Daniel Weix
Keyword(s):  
Carboxylic Acid ◽  
Solid Support ◽  
Reaction Conditions ◽  
Decarboxylative Coupling ◽  
New Strategy ◽  
The Cross ◽  
Acyl Donors ◽  
Acid Esters

A new strategy for the synthesis of ketones is presented based upon the decarboxylative coupling of N-hydroxyphthalimide (NHP) esters with S-2-pyridyl thioesters. The reactions are selective for the cross-coupled product because NHP esters act as radical donors and the thioesters act as acyl donors. The reaction conditions are general and mild, with over 40 examples presented, including larger fragments and the 20-mer peptide Exendin(9-39) on solid support.

Aliphatic Carboxylic Acid as Hydrogen-Bond Donor for Converting CO2 and Epoxide into Cyclic Carbonate under Mild Conditions

2021 ◽  
Author(s):  
Zheng Wang ◽  
Yajun Wang ◽  
Qianjie Xie ◽  
Zhiying Fan ◽  
Yehua Shen
Keyword(s):  
Hydrogen Bond ◽  
Carboxylic Acid ◽  
Value Added ◽  
Cyclic Carbonate ◽  
Hydrogen Bond Donor ◽  
Title Reaction ◽  
Aliphatic Carboxylic Acid ◽  
Mild Conditions ◽  
Atmospheric Carbon

The coupling of CO2 and epoxide is promising way to reduce atmospheric carbon by converting it into value-added cyclic carbonate. Pursuing efficient catalysts is highly attractive for the title reaction....

ChemInform Abstract: Practical Syntheses of Functionalized 1-Oxo-1,2,3,4-tetrahydro-β- carboline-3-carboxylic Acid Esters.

ChemInform ◽  
2010 ◽  
Vol 27 (33) ◽  
pp. no-no
Author(s):  
L. JEANNIN ◽  
J. SAPI ◽  
E. VASSILEVA ◽  
P. RENARD ◽  
J.-Y. LARONZE
Keyword(s):  
Carboxylic Acid ◽  
Acid Esters

Synthesis of Ethers by GaBr3-Catalyzed Reduction of Carboxylic Acid Esters and Lactones by Siloxanes

ChemSusChem ◽  
2013 ◽  
Vol 7 (2) ◽  
pp. 644-649 ◽  
Author(s):  
Ursula Biermann ◽  
Jürgen O. Metzger
Keyword(s):  
Carboxylic Acid ◽  
Acid Esters

Preparation of unsaturated carboxylic acid esters with metallosilicate catalysts

Zeolites ◽  
1995 ◽  
Vol 15 (1) ◽  
pp. 84
Author(s):  
H. Nakajima ◽  
T. Fujii ◽  
K. Kitagawa
Keyword(s):  
Carboxylic Acid ◽  
Unsaturated Carboxylic Acid ◽  
Acid Esters

6-Methylergoline-8-carboxylic acid esters as serotonin antagonists: N1-substituent effects on 5HT2 receptor affinity

1987 ◽  
Vol 30 (10) ◽  
pp. 1823-1826 ◽  
Author(s):  
Gifford Marzoni ◽  
William L. Garbrecht ◽  
Pawel Fludzinski ◽  
Marlene L. Cohen
Keyword(s):  
Carboxylic Acid ◽  
Substituent Effects ◽  
Serotonin Antagonists ◽  
Receptor Affinity ◽  
5Ht2 Receptor ◽  
Acid Esters
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