Synthesis and characterization of acrylated phosphonates and their polymers having 1,3-dioxolane and 1,3-dioxane moieties derived from brominated cyclic acetals of polyols through the Arbuzov reaction. II

1988 ◽  
Vol 26 (12) ◽  
pp. 3251-3268 ◽  
Author(s):  
Suresh K. Sahni ◽  
Israel Cabasso
Keyword(s):  
Synthesis And Characterization ◽  
Arbuzov Reaction ◽  
Cyclic Acetals ◽  
The Arbuzov Reaction

Synthesis and characterization of two bifunctional pyrazole-phosphonic acid ligands

2019 ◽  
Vol 74 (11-12) ◽  
pp. 891-899 ◽  
Author(s):  
Bahareh Nateghi ◽  
Christoph Janiak
Keyword(s):  
Phosphonic Acid ◽  
Acid Ester ◽  
Synthesis And Characterization ◽  
Arbuzov Reaction ◽  
Acidic Hydrolysis ◽  
Bifunctional Compounds ◽  
Alternative Routes ◽  
The Arbuzov Reaction ◽  
Hydrogen Bonded

AbstractThe bifunctional compounds 3,5-dimethyl-4-(4-phosphonophenyl)-1H-pyrazole 1 and 4-(4-phosphonophenyl)-1H-pyrazole 2 were synthesized via Suzuki-Miyaura coupling, starting from a Boc-protected pyrazolylboronic acid ester and the iodoarylphosphonate. The target compounds were isolated after acidic hydrolysis in the form of the hydrochloride salts 1 · HCl and 2 · HCl · H2O with a yield of 81% and 86%, respectively. Pd(dppf)Cl2 was found to be superior to Pd(PPh3)4 as a catalyst; dry 1,4-dioxane as a solvent, Cs2CO3 as a base, and no co-ligands were the best found conditions. The alternative routes through iodoarylphosphonate of iodoarylpyrazole, with the crucial steps based on the copper-catalyzed coupling with acetylacetone or the Arbuzov reaction were proven inefficient. The structures of the isolated hydrochloride salts 1 · HCl and 2 · HCl · H2O feature hydrogen-bonded networks involving the chloride anions.

Synthesis and Characterization of the Three Dicyclopentapyrenes

1996 ◽  
Vol 61 (10) ◽  
pp. 3572-3572
Author(s):  
Lawrence T. Scott ◽  
Atena Necula
Keyword(s):  
Synthesis And Characterization

Synthesis and characterization of TiN / Ti / AISI 410 coatings

2018 ◽  
Vol 2 (1) ◽  
pp. 7
Author(s):  
S Chirino ◽  
Jaime Diaz ◽  
N Monteblanco ◽  
E Valderrama
Keyword(s):  
Synthesis And Characterization ◽  
Photoemission Spectroscopy ◽  
X Ray Diffraction ◽  
X Ray ◽  
Columnar Grains ◽  
Tin Thin Films ◽  
Steel Aisi ◽  
Interacting Surfaces ◽  
Stainless Steel Aisi

The synthesis and characterization of Ti and TiN thin films of different thicknesses was carried out on a martensitic stainless steel AISI 410 substrate used for tool manufacturing. The mechanical parameters between the interacting surfaces such as thickness, adhesion and hardness were measured. By means of the scanning electron microscope (SEM) the superficial morphology of the Ti/TiN interface was observed, finding that the growth was of columnar grains and by means of EDAX the existence of titanium was verified.  Using X-ray diffraction (XRD) it was possible to observe the presence of residual stresses (~ -3.1 GPa) due to the different crystalline phases in the coating. Under X-ray photoemission spectroscopy (XPS) it was possible to observe the molecular chemical composition of the coating surface, being Ti-N, Ti-N-O and Ti-O the predominant ones.

Synthesis and characterization of zeolite-encapsulated porphyrins

2009 ◽  
Author(s):  
Marziye Javaheri Kachousangi ◽  
Rahmatollah Rahimi ◽  
Mohamad Mehdi Kashani-Motlagh
Keyword(s):  
Synthesis And Characterization
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