Click chemistry in materials synthesis. 1. Adhesive polymers from copper-catalyzed azide-alkyne cycloaddition

2004 ◽  
Vol 42 (17) ◽  
pp. 4392-4403 ◽  
Author(s):  
David D. Díaz ◽  
Sreenivas Punna ◽  
Philipp Holzer ◽  
Andrew K. McPherson ◽  
K. Barry Sharpless ◽  
...  
Keyword(s):  
Click Chemistry ◽  
Materials Synthesis

Thiol–ene “click” reactions and recent applications in polymer and materials synthesis: a first update

2014 ◽  
Vol 5 (17) ◽  
pp. 4820-4870 ◽  
Author(s):  
Andrew B. Lowe
Keyword(s):  
Click Chemistry ◽  
Polymer Materials ◽  
Materials Synthesis ◽  
Efficient Tool ◽  
Click Reactions ◽  
Previous Review

This contribution serves as an update to a previous review (Polym. Chem.2010,1, 17–36) and highlights recent applications of thiol–ene ‘click’ chemistry as an efficient tool for both polymer/materials synthesis as well as modification.

Thiol-yne click chemistry: A powerful and versatile methodology for materials synthesis

2010 ◽  
Vol 20 (23) ◽  
pp. 4745 ◽  
Author(s):  
Andrew B. Lowe ◽  
Charles E. Hoyle ◽  
Christopher N. Bowman
Keyword(s):  
Click Chemistry ◽  
Materials Synthesis

Click chemistry in materials synthesis. III. Metal-adhesive polymers from Cu(I)-catalyzed azide-alkyne cycloaddition

2007 ◽  
Vol 45 (22) ◽  
pp. 5182-5189 ◽  
Author(s):  
Yi Liu ◽  
David D. Díaz ◽  
Adrian A. Accurso ◽  
K. Barry Sharpless ◽  
Valery V. Fokin ◽  
...  
Keyword(s):  
Click Chemistry ◽  
Materials Synthesis

Bringing Efficiency to Materials Synthesis: The Philosophy of Click Chemistry

ChemInform ◽  
2007 ◽  
Vol 38 (40) ◽  
Author(s):  
Craig J. Hawker ◽  
Valery V. Fokin ◽  
M. G. Finn ◽  
K. Barry Sharpless
Keyword(s):  
Click Chemistry ◽  
Materials Synthesis

Bringing Efficiency to Materials Synthesis: The Philosophy of Click Chemistry

2007 ◽  
Vol 60 (6) ◽  
pp. 381 ◽  
Author(s):  
Craig J. Hawker ◽  
Valery V. Fokin ◽  
M. G. Finn ◽  
K. Barry Sharpless
Keyword(s):  
Click Chemistry ◽  
Materials Synthesis

Click Chemistry Expedited Radiosynthesis: Sulfur [18F]fluoride Exchange of Aryl Fluorosulfates

2019 ◽  
Author(s):  
Qinheng Zheng ◽  
Hongtao Xu ◽  
Hua Wang ◽  
Wen-Ge Han Du ◽  
Nan Wang ◽  
...  
Keyword(s):  
Click Chemistry ◽  
High Performance ◽  
Isotopic Exchange ◽  
Tumor Imaging ◽  
Radiochemical Yield ◽  
Exchange Method ◽  
Molar Activity ◽  
Positron Emission ◽  
Sulfur Fluoride

The lack of simple, efficient [<sup>18</sup>F]fluorination processes and new target-specific organofluorine probes remains the major challenge of fluorine-18-based positron emission tomography (PET). We report here a fast isotopic exchange method for the radiosynthesis of aryl [<sup>18</sup>F]fluorosulfate based PET agents enabled by the emerging sulfur fluoride exchange (SuFEx) click chemistry. The method has been applied to the fully-automated <sup>18</sup>F-radiolabeling of twenty-five structurally diverse aryl fluorosulfates with excellent radiochemical yield (83–100%) and high molar activity (up to 281 GBq µmol<sup>–1</sup>) at room temperature in 30 seconds. The purification of radiotracers requires no time-consuming high-performance liquid chromatography (HPLC), but rather a simple cartridge filtration. The utility of aryl [<sup>18</sup>F]fluorosulfate is demonstrated by the <i>in vivo</i> tumor imaging by targeting poly(ADP-ribose) polymerase 1 (PARP1).

Novel CO2-Thermic Oxidation Process with Mg-Based Intermetallic Compounds and Its Application to Energy Storage Materials

2018 ◽  
Author(s):  
Younghwan Cha ◽  
Jung-In Lee ◽  
Panpan Dong ◽  
Xiahui Zhang ◽  
Min-Kyu Song
Keyword(s):  
Intermetallic Compounds ◽  
Oxidation Process ◽  
Value Added ◽  
Energy Storage Materials ◽  
Reaction Products ◽  
Materials Synthesis ◽  
Energy Materials ◽  
A Value ◽  
Carbon Coated ◽  
Novel Strategy

A novel strategy for the oxidation of Mg-based intermetallic compounds using CO<sub>2</sub> as an oxidizing agent was realized via simple thermal treatment, called ‘CO2-thermic Oxidation Process (CO-OP)’. Furthermore, as a value-added application, electrochemical properties of one of the reaction products (carbon-coated macroporous silicon) was evaluated. Considering the facile tunability of the chemical/physical properties of Mg-based intermetallics, we believe that this route can provide a simple and versatile platform for functional energy materials synthesis as well as CO<sub>2</sub> chemical utilization in an environment-friendly and sustainable way.

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