Effect of Lithium Doping on the Structures and CO 2 Adsorption Properties of Metal‐Organic Frameworks HKUST‐1

2018 ◽  
Vol 3 (45) ◽  
pp. 12865-12870 ◽  
Author(s):  
Lingling Zhou ◽  
Zhaodong Niu ◽  
Xu Jin ◽  
Lihong Tang ◽  
Liping Zhu
Keyword(s):  
Metal Organic Frameworks ◽  
Adsorption Properties ◽  
Lithium Doping ◽  
Metal Organic

Enhancement of Carbon Dioxide Adsorption by Lithium Decorating and Fullerene Encapsulating in Metal-Organic Frameworks

2013 ◽  
Vol 773 ◽  
pp. 927-931
Author(s):  
Rui Feng Lu ◽  
De Wei Rao ◽  
Zhao Shun Meng ◽  
Kai Ming Deng
Keyword(s):  
Metal Organic Frameworks ◽  
Carbon Dioxide Adsorption ◽  
Grand Canonical Monte Carlo ◽  
Ambient Conditions ◽  
Li Doping ◽  
Lithium Doping ◽  
Crystal Density ◽  
Metal Organic ◽  
Density Surface ◽  
Grand Canonical

Using grand canonical Monte Carlo method, the capacities of CO2adsorption in IRMOF-12 and-14 are simulated at ambient conditions. We have theoretically found that CO2uptake can be greatly enhanced by either lithium doping or fullerene impregnating, and the influence of the Li doping is more significant than that of C60impregnation. Furthermore, the CO2storage capacities of IRMOFs after both Li doping and C60impregnating are improved to be about 30 times those of corresponding pristine structures. To further understand the mechanism, we analyzed the distribution pattern of CO2adsorption in materials and investigated the relationships between CO2uptakes and crystal density, surface area per volume and per mass, and pore volume per volume and per mass in detail.

Lithium doping on metal-organic frameworks for enhancing H2 Storage

2012 ◽  
Vol 37 (1) ◽  
pp. 946-950 ◽  
Author(s):  
Zhonghua Xiang ◽  
Zan Hu ◽  
Wantai Yang ◽  
Dapeng Cao
Keyword(s):  
Metal Organic Frameworks ◽  
Lithium Doping ◽  
Metal Organic

New Functionalized Metal–Organic Frameworks MIL-47-X (X = −Cl, −Br, −CH3, −CF3, −OH, −OCH3): Synthesis, Characterization, and CO2 Adsorption Properties

2013 ◽  
Vol 117 (44) ◽  
pp. 22784-22796 ◽  
Author(s):  
Shyam Biswas ◽  
Danny E. P. Vanpoucke ◽  
Toon Verstraelen ◽  
Matthias Vandichel ◽  
Sarah Couck ◽  
...  
Keyword(s):  
Co2 Adsorption ◽  
Metal Organic Frameworks ◽  
Adsorption Properties ◽  
Metal Organic

Xe adsorption and separation properties of a series of microporous metal–organic frameworks (MOFs) with V-shaped linkers

2017 ◽  
Vol 5 (32) ◽  
pp. 16611-16615 ◽  
Author(s):  
Debasis Banerjee ◽  
Sameh K. Elsaidi ◽  
Praveen K. Thallapally
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Frameworks ◽  
Adsorption Properties ◽  
Metal Organic

A series of microporous metal–organic frameworks (MOFs) constructed by using a V-shaped linker, 4,4′-sulfonyldibenzoic acid, were evaluated for their Xe gas adsorption properties.

Tuning the interpenetration of metal–organic frameworks through changing ligand functionality: effect on gas adsorption properties

CrystEngComm ◽  
2020 ◽  
Vol 22 (3) ◽  
pp. 506-514 ◽  
Author(s):  
Bin Li ◽  
Qing-Qing Yan ◽  
Zhi-Qiang Xu ◽  
Ying-Bo Xu ◽  
Guo-Ping Yong
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Frameworks ◽  
Adsorption Properties ◽  
Metal Organic

Two interpenetrated MOFs are constructed with a 2-connected ligand, whereas one non-interpenetrated MOF is constructed by using a 3-connected ligand.

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