Bonding Situation in “Early-Late” Transition Metal Complexes Cl3M-M′(PCl3)4 (M = Ti, Zr, Hf; M′ = Co, Rh, Ir) - Theoretical Study for a Ligand Fine Tuning of M-M′ Bonds

2011 ◽  
Vol 637 (12) ◽  
pp. 1728-1735 ◽  
Author(s):  
Nozomi Takagi ◽  
Andreas Krapp ◽  
Gernot Frenking
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Theoretical Study ◽  
Fine Tuning ◽  
Late Transition Metal ◽  
Late Transition ◽  
Early Late

Formation of metal-radical species upon reduction of late transition metal complexes with heteroleptic ligands: an experimental and theoretical study

2020 ◽  
Vol 44 (30) ◽  
pp. 13195-13206
Author(s):  
Michal Malček ◽  
Júlia Kožíšková ◽  
Peter Herich ◽  
Peter Rapta ◽  
Iryna Stepanenko ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Broad Spectrum ◽  
Theoretical Study ◽  
Late Transition Metal ◽  
Radical Species ◽  
Broad Spectrum Antibiotics ◽  
Late Transition ◽  
Metal Radical

Three novel transition metal complexes with selenadiazoloquinolones as potential broad spectrum antibiotics in clinical praxis.

Catalytic polymerization of propylene by heterobimetallic bridged early/late transition metal complexes

1998 ◽  
Vol 129 (2-3) ◽  
pp. 191-198 ◽  
Author(s):  
Tal Shribman ◽  
Stefan Kurz ◽  
Uwe Senff ◽  
Frank Lindberg ◽  
Evamarie Hey-Hawkins ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Late Transition Metal ◽  
Catalytic Polymerization ◽  
Late Transition ◽  
Early Late

Novel Early-late Transition Metal Complexes. The First Thiolato Bridged Titanium-Ruthenium Complexes

1997 ◽  
Vol 26 (1) ◽  
pp. 57-58 ◽  
Author(s):  
Ken-ichi Fujita ◽  
Masakazu Ikeda ◽  
Teruyuki Kondo ◽  
Take-aki Mitsudo
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Ruthenium Complexes ◽  
Late Transition Metal ◽  
Late Transition ◽  
Early Late

Hydrosilylation as an efficient tool for polymer synthesis and modification with methacrylates

RSC Advances ◽  
2015 ◽  
Vol 5 (8) ◽  
pp. 5879-5885 ◽  
Author(s):  
Nuttapol Risangud ◽  
Zhijian Li ◽  
Athina Anastasaki ◽  
Paul Wilson ◽  
Kristian Kempe ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Polymer Synthesis ◽  
Late Transition Metal ◽  
Efficient Tool ◽  
Silicon Compounds ◽  
Late Transition

Hydrosilylation is a well-established reaction for the preparation of organo-silicon compounds, in which vinyl groups react with silanes (Si–H) usually catalysed by late transition metal complexes, most often Pt(ii) complexes.

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