Theoretical Study of Cp2Zr-, (MeO)2Zr-, and M(PH3)-Mediated Coupling Reactions of Acetylenes (M = Ni, Pt). Significant Differences between Early- and Late-Transition-Metal Complexes

2005 ◽  
Vol 24 (9) ◽  
pp. 2129-2140 ◽  
Author(s):  
Tomonari Imabayashi ◽  
Yusuke Fujiwara ◽  
Yoshihide Nakao ◽  
Hirofumi Sato ◽  
Shigeyoshi Sakaki
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Theoretical Study ◽  
Late Transition Metal ◽  
Coupling Reactions ◽  
Late Transition

Formation of metal-radical species upon reduction of late transition metal complexes with heteroleptic ligands: an experimental and theoretical study

2020 ◽  
Vol 44 (30) ◽  
pp. 13195-13206
Author(s):  
Michal Malček ◽  
Júlia Kožíšková ◽  
Peter Herich ◽  
Peter Rapta ◽  
Iryna Stepanenko ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Broad Spectrum ◽  
Theoretical Study ◽  
Late Transition Metal ◽  
Radical Species ◽  
Broad Spectrum Antibiotics ◽  
Late Transition ◽  
Metal Radical

Three novel transition metal complexes with selenadiazoloquinolones as potential broad spectrum antibiotics in clinical praxis.

Hydrosilylation as an efficient tool for polymer synthesis and modification with methacrylates

RSC Advances ◽  
2015 ◽  
Vol 5 (8) ◽  
pp. 5879-5885 ◽  
Author(s):  
Nuttapol Risangud ◽  
Zhijian Li ◽  
Athina Anastasaki ◽  
Paul Wilson ◽  
Kristian Kempe ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Polymer Synthesis ◽  
Late Transition Metal ◽  
Efficient Tool ◽  
Silicon Compounds ◽  
Late Transition

Hydrosilylation is a well-established reaction for the preparation of organo-silicon compounds, in which vinyl groups react with silanes (Si–H) usually catalysed by late transition metal complexes, most often Pt(ii) complexes.

Electron-density distributions in selected ferrocenyl-pyrazolyl late transition-metal complexes

2018 ◽  
Vol 20 (17) ◽  
pp. 11682-11691
Author(s):  
M. A. Peck ◽  
G. R. Hearne ◽  
C. Obuah ◽  
J. Darkwa
Keyword(s):  
Mössbauer Spectroscopy ◽  
Transition Metal ◽  
Metal Complexes ◽  
Electron Density ◽  
Transition Metal Complexes ◽  
Mossbauer Spectroscopy ◽  
Late Transition Metal ◽  
Density Distributions ◽  
Mößbauer Spectroscopy ◽  
Late Transition

57Fe Mössbauer spectroscopy has been used to study electronic dispersions in complexes of Fe, Co, Ni and Pd anchored onto 3-ferrocenyl-5-methylpyrazolylmethylenepyridine and 3-ferrocenylpyrazolylmethylenepyridine ligands.

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