Iron-based amorphous metallic alloys (AMAs) of several compositions were exposed to neutron irradiation with fluences of up to 1019 n/cm2. These materials exhibit excellent magnetic properties which predetermine them for use in electronic devices operated also in radiation-exposed environments. Response of the studied AMAs to neutron irradiation is followed by Mössbauer spectrometry which probes the local microstructure. Neutron irradiation leads to rearrangement of constituent atoms, their clustering, and formation of stress centers. The observed modifications of topological short-range order result in changes of spectral parameters including average hyperfine magnetic field, , standard deviation of the distribution of hyperfine fields, and position of the net magnetic moment. After irradiation, especially differences in -values develop in two opposite directions. This apparent controversy can be explained by formation of specific atomic pairs with different exchange interactions, which depend on the composition of the samples. Part II of this paper will be devoted to radiation effects caused in Fe-based AMAs by ion irradiation.
Radiation Effects in Amorphous Metallic Alloys as Revealed by Mössbauer Spectrometry: Part I. Neutron Irradiation
