Evaluation of Surface Tension and Tolman Length as a Function of Droplet Radius from Experimental Nucleation Rate and Supersaturation Ratio

2007 ◽  
pp. 62-68
Author(s):  
A. A. Onischuk ◽  
S. V. Vosel ◽  
P. A. Purtov ◽  
A. M. Baklanov
Keyword(s):  
Surface Tension ◽  
Nucleation Rate ◽  
Droplet Radius ◽  
Supersaturation Ratio ◽  
Tolman Length

Surface Tension and Tolman Length of Spherical Particulate in Contact with Fluid

2008 ◽  
Vol 112 (24) ◽  
pp. 7251-7256 ◽  
Author(s):  
Yongjin He ◽  
Jianguo Mi ◽  
Chongli Zhong
Keyword(s):  
Surface Tension ◽  
Tolman Length

The Effect of Microdroplet Size on the Surface Tension and Tolman Length

2011 ◽  
Vol 115 (1) ◽  
pp. 109-112 ◽  
Author(s):  
Yong-Qiang Xue ◽  
Xin-Cheng Yang ◽  
Zi-Xiang Cui ◽  
Wei-Peng Lai
Keyword(s):  
Surface Tension ◽  
Tolman Length

Studies on nucleation and crystal growth kinetics of plutonium(IV) oxalatex

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Chuanbo Li ◽  
Bo Wang ◽  
Xiang Li ◽  
Taihong Yan ◽  
Weifang Zheng
Keyword(s):  
Growth Rate ◽  
Crystal Growth ◽  
Nucleation Rate ◽  
Crystal Growth Rate ◽  
Acid Solutions ◽  
Dilution Ratio ◽  
Secondary Nucleation ◽  
Supersaturation Ratio ◽  
Crystal Growth Kinetics ◽  
Kinetics Of

Abstract A new method is developed to calculate the dilution ratio N of the two reactant solutions during nucleation rate determination. When the initial apparent supersaturation ratio S N  = f(N) in the dilution tank is controlled between 1.66 and 1.67, the counted nuclei is the most, both nuclei dissolving and secondary nucleation avoided satisfactorily. Based on this methoed, Plutonium(IV) oxalate is precipitated by mixing equal volumes of tetravalent plutonium nitrate and oxalic acid solutions. Experiments are carried out by varying the supersaturation ratio from 8.37 to 22.47 and temperature from 25 to 50 °C. The experimental results show that the nucleation rate of plutonium(IV) oxalate in the supersaturation range cited above can be expressed by the equation R N  = A N exp(−E a /RT)exp[−B/(ln S)2], where A N  = 4.8 × 1023 m−3 s−1 , and E a  = 36.2 kJ mol−1, and B = 20.2. The crystal growth rate of plutonium(IV) oxalate is determined by adding seed crystals into a batch crystallizer. The crystal growth rate can be expressed by equation G(t) = k g exp(−E’ a /RT) (c − c eq) g , where k g  = 7.3 × 10−7 (mol/L)−1.1(m/s), E’ a  = 25.7 kJ mol−1, and g = 1.1.

Curvature Dependence and Tolman Length of Surface Tension of Nano-Droplet of Attractive Hard Sphere Liquid

2015 ◽  
Vol 12 (12) ◽  
pp. 5654-5658
Author(s):  
Xiao-Song Wang ◽  
Zhi-Bo Yang ◽  
Aijun Hu ◽  
Long Zhou ◽  
Bao-Zhan Lv
Keyword(s):  
Surface Tension ◽  
Hard Sphere ◽  
Hard Sphere Liquid ◽  
Tolman Length ◽  
Curvature Dependence
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