High Resolution Particle Size Analysis of Coating Materials

Author(s):  
John C. Thomas ◽  
David Fairhurst
2014 ◽  
Vol 974 ◽  
pp. 183-187 ◽  
Author(s):  
K. Meekhanthong ◽  
S. Wirojanupatump

Thermal spray coatings have become one of the most potential for hard chrome replacement, particularly for wear and corrosion applications. In this study four types of hard coating materials were selected and thermally sprayed by suitable processes as the following designated codes (material/spray technique): Cr-Fe/HVOF, Cr-Ni/HVOF, WC-Ni/SF and Cr-Fe/AS. All of starting materials were characterized in order to create a correlation between spray materials and coating characteristics. SEM was employed for morphology and microstructure investigation. Particle size analysis was investigated by SEM and laser particle size analyzer. Coating characterization included surface roughness measurment by profilometer, porosity evaluation by image analysis and hardness test by Vicker microhardness tester. Microstructure of coatings was also revealed by SEM. Wear performance was evaluated by pin on disc test and dry sand rubber wheel abrasion test. Corrosion resistance was tested by potentiodynamic method. The results showed that particle size and morphology of starting powders were various depending on manufacturing method. Chemical compositions of starting materials showed great effect on coating properties and performance. Coatings deposited by HVOF and spray & fuse (SF) method showed typically dense and homogeneous structure than arc sprayed coating. WC-Ni/SF coating showed lowest abrasive wear rate compared to other thermally sprayed coatings. All Ni base coatings had significantly lower corrosion rates while Cr-Ni/HVOF coating had lowest corrosion rate. Although Cr-Ni/HVOF and WC-Ni/SF could be applicable for both wear and corrosion applications, for heat sensitive parts, Cr-Ni/HVOF coating could be a better alternative to spray and fuse.


Clay Minerals ◽  
1993 ◽  
Vol 28 (4) ◽  
pp. 531-537 ◽  
Author(s):  
P. McFadyen ◽  
D. Fairhurst

AbstractModem disc centrifuge technology has extended the range of application of sedimentation particle size analysis to include the submicron region. An overall size range of approximately 10 nm to 100 pm is now accessible. The principles of both the disc centrifuge photosedimentometer, which employs optical detection with full Mie light scattering corrections, and the X-ray disc centrifuge are described. Examples of their application to a variety of samples are given to illustrate the performance characteristics of the instruments including a direct comparison of resolving power with that of the laser diffraction technique.


2017 ◽  
Vol 46 (5) ◽  
pp. 342-355 ◽  
Author(s):  
Petr Benda ◽  
Andréa Kalendová

Purpose The aim of the work is to develop an anticorrosion pigment based on an oxide mixture with lamellar particles. The pigments are prepared from lamellar zinc, zinc oxide and magnetite by calcination. An alkaline earth carbonate is added when embedding a third cation in the lattice of the ferrite that forms the envelope of the lamellar zinc. The properties of the pigments are tested both in the powdered state and when embedded in an epoxy-ester system using different pigment volume concentrations (PVC). Design/methodology/approach The properties of paints containing synthesised oxide mixture-based pigments at various volume concentrations and with the Q factor – Q = PVC/CPVC = 0.65 – were examined (where CPVC is critical pigment volume concentration). A series of isometric ferrite pigments were also synthesised for a comparison. Paints of both types with PVC = 10, 15 and 20 per cent were formulated. Steel panels coated with the paints were subjected to corrosion and mechanical tests. Findings The oxide mixtures with lamellar particles were subjected to particle size analysis and found to make up a broad distribution curve. Electron microscopy photographs confirmed that the oxide mixture pigments contained lamellar particles with a surface layer. A high anticorrosion effect was achieved owing to the combination of different oxide types. Research limitations/implications The properties of the oxide mixtures with lamellar particles are described. Their particle distribution curves can be obtained by particle size analysis methods with a view to obtaining additional information on the status and properties of the pigment particles that may be useful in the development of better paints/coating materials. Practical implications Oxide mixtures with lamellar particles can be used in paints protecting construction steel. Originality/value The composition of the prepared oxide mixture-based pigments is novel. Each oxide acts by its own anticorrosion mechanism and the final beneficial effect is due to their concerted action.


1991 ◽  
Vol 7 (4) ◽  
pp. 377-379 ◽  
Author(s):  
John C. Thomas ◽  
Anton P. J. Middelberg ◽  
Jean Francois Hamel ◽  
Mark A. Snoswell

Geomorphology ◽  
2014 ◽  
Vol 221 ◽  
pp. 51-68 ◽  
Author(s):  
David W. Clarke ◽  
John F. Boyle ◽  
Richard C. Chiverrell ◽  
Javier Lario ◽  
Andrew J. Plater

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