57Fe quadrupole splitting and isomer shift in various oxyhemoglobins: study using Mössbauer spectroscopy

2010 ◽  
pp. 301-307
Author(s):  
M. I. Oshtrakh ◽  
A. L. Berkovsky ◽  
A. Kumar ◽  
S. Kundu ◽  
A. V. Vinogradov ◽  
...  
Keyword(s):  
Mössbauer Spectroscopy ◽  
Isomer Shift ◽  
Quadrupole Splitting ◽  
Mossbauer Spectroscopy ◽  
Mößbauer Spectroscopy

Mössbauer Spectroscopic Studies of Monosubstituted Pentacyano Ferrate(II) Complexes, Na3[Fe(CN)5RNH2] · nH2O

1981 ◽  
Vol 36 (1) ◽  
pp. 59-61 ◽  
Author(s):  
A. N. Garg ◽  
P. N. Shukla
Keyword(s):  
Mössbauer Spectroscopy ◽  
Isomer Shift ◽  
Quadrupole Splitting ◽  
Electron Density ◽  
Mossbauer Spectroscopy ◽  
Spectroscopic Studies ◽  
Limited Range ◽  
Octahedral Geometry ◽  
Amino Groups ◽  
Mößbauer Spectroscopy

Abstract A series of compounds Na3[Fe(CN)5RNH2] · nH2O where R = -H, -CH3, -C2H5, n-C3H7, n-C4H9 and -CH2C6H5 and RNH2 = C5H5N have been studied by Mössbauer spectroscopy. Quadrupole splitting (⊿EQ) values vary in a limited range (0.68-0.80 mm/sec) indicating only small distortions in the octahedral geometry of the compounds with the substitution of various amino groups. Isomer shift (δ) values remain almost constant suggesting that s-electron density is not affected by substitution.

57Fe quadrupole splitting and isomer shift in various oxyhemoglobins: study using Mössbauer spectroscopy

2010 ◽  
Vol 197 (1-3) ◽  
pp. 301-307 ◽  
Author(s):  
M. I. Oshtrakh ◽  
A. L. Berkovsky ◽  
A. Kumar ◽  
S. Kundu ◽  
A. V. Vinogradov ◽  
...  
Keyword(s):  
Mössbauer Spectroscopy ◽  
Isomer Shift ◽  
Quadrupole Splitting ◽  
Mossbauer Spectroscopy ◽  
Mößbauer Spectroscopy

An Investigation of the Sn1−x SbxO2 System by Mössbauer Spectroscopy

1973 ◽  
Vol 51 (13) ◽  
pp. 2077-2081 ◽  
Author(s):  
T. Birchall ◽  
R. J. Bouchard ◽  
R. D. Shannon
Keyword(s):  
Mössbauer Spectroscopy ◽  
Isomer Shift ◽  
Quadrupole Splitting ◽  
Electron Density ◽  
Conduction Band ◽  
Mossbauer Spectroscopy ◽  
Oxidation States ◽  
Conduction Electrons ◽  
Mößbauer Spectroscopy

The Sn1−xSbxO2 system has been studied by means of 119Sn and 121Sb Mössbauer spectroscopy. The presence of an unresolved quadrupole splitting in SnO2 is confirmed. The data show that the oxidation states of the tin and antimony are IV and V, respectively. The conduction electrons resulting from Sb substitution are distributed over the entire lattice. As the Sb content increases, the 119Sn isomer shift and s electron density at the Sn nucleus also increase, as expected for a conduction band composed largely of Sn 5s orbitals.

Quadrupole splitting observed in some cubic Tm compounds by169Tm Mössbauer spectroscopy

1983 ◽  
Vol 16 (1-4) ◽  
pp. 721-724 ◽  
Author(s):  
P. C. M. Gubbens ◽  
A. M. van der Kraan ◽  
K. H. J. Buschow
Keyword(s):  
Mössbauer Spectroscopy ◽  
Quadrupole Splitting ◽  
Mossbauer Spectroscopy ◽  
Mößbauer Spectroscopy
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