4M method – new application of Mössbauer spectroscopy to classification of meteorites. How it works?

Abstract4M method is a new application of Mössbauer spectroscopy to quantitative classification of ordinary chondrites. 4M derives from four words: meteorites, Mössbauer spectroscopy, multidimensional discriminant analysis, Mahalanobis distance. This method was published by us in 2019. In this paper we present application of 4M method to classification of four meteorites. Link to script with calculation needed for classification of ordinary chondrites was given.

Can Mӧssbauer methods of classifying ordinary chondrites help to identify non-representative samples of these meteorites?

Mössbauer spectra of nonweathered ordinary chondrites consist of four main mineral phases: olivines, pyroxenes, metallic phase and troilite. These minerals represent more than 95% of the whole mass of an ordinary chondrite. Distribution of these mineral phases in micro-scale is not homogeneous. Nevertheless, preparation of representative sample of ordinary chondrite for Mössbauer measurements is possible. To do that a part of 1 g nonweathered material, selected from inside of meteorite without any specific intention is needed. The Warsaw group has been working on investigation of meteorites for 25 years and has analysed about 150 Mössbauer spectra of various meteorites. Among them we found 15 spectra, which could be suspected of being non-representative. These spectra were obtained from Baszkówka, Amber, Bjurböle, Krasnoi-Ugol and Chelyabinsk meteorites. The analysis of how the samples of meteorites were selected for investigation, has shown that the non-representativeness of samples may be due to: intentional choice of sample, preparation of sample from a too small part of material or the use of non-credible source of meteoritic samples. For confirmation of these assumptions, we used a new method of classification of ordinary chondrites – the 4M method. It turned out that this method is a very useful tool for investigation of non-representative samples of equilibrated ordinary chondrites.

Developing Prototype Simulants for Surface Materials and Morphology of Near Earth Asteroid 2016 HO3

There are a variety of applications for asteroid simulants in asteroid studies for science advances as well as technology maturation. For specific purpose, it usually requires purpose-specialized simulant. In this study, we designed and developed a set of prototype simulants as S-type asteroid surface materials analogue based on H, L, and LL ordinary chondrites’ mineralogy and terrestrial observations of near-earth asteroid 2016 HO3, which is the Chinese sample return mission target. These simulants are able to simulate morphology and reflectance characteristics of asteroid (469219) 2016 HO3 and, thus, to be used for engineering evaluation of the optical navigation system and the sampling device of the spacecraft during the mission phase. Meanwhile, these prototype simulants are easily to modify to reflect new findings on the asteroid surface when the spacecraft makes proximate observations.

Fe, Ni, Co, and Cu in FeNi alloys of H Chondrites

This publication presents the results of chemical analyses of 173 FeNi alloy grains from four selected H ordinary chondrites: Thuathe, Chergach, Gao-Guenie and NWA 4555. Based on performed analyses and calculations, the following average chemical composition of the FeNi alloy was determined [in wt.%]: Fe - 90.75%; Ni - 8.80%; Co - 0.35%; Cu - 0.03%. The content of Cu and Co depends on the nickel content in the FeNi alloy. The low-nickel alloy represented by kamacite is enriched in cobalt (average content 0.38%) and depleted in copper (0.01%), while the high-nickel alloy, represented mainly by taenite, is characterized by a low content of cobalt (0.08%), and a significant enrichment in copper (0.16%). Based on these data, it is possible to approximate the resources of these metals in the parent bodies of these chondrites. For example, for the asteroid (143624) 2003 HMi6, which is classified as a Near Earth Object (NEO), such resources are [in Mg]: Fe - 2.4 · 109, Ni - 2.3 · 108, Co-9.2 · 106, Cu-7.9 · 105.