We present measurements of B → PV and VV decays based on 140 fb-1 of data recorded at the ϒ(4S) resonance with the Belle detector at the KEKB e+e- storage ring. Branching fractions of B → ηK*, ηρ+, ρπ0, and ρ+K* are measured; while upper limits of B → ηρ0 and ρ0K* decays are given. The polarization study of B → ϕK* is also updated.