Kinetics and mechanism of an unique hydrolysis reaction of (hexafluoroacetylacetonato)bis(ethylenediamine)cobalt(III) in aqueous solution

1984 ◽  
Vol 9 (7) ◽  
pp. 257-259 ◽  
Author(s):  
Y. Kitamura ◽  
R. van Eldik
Keyword(s):  
Aqueous Solution ◽  
Kinetics And Mechanism ◽  
Hydrolysis Reaction

Kinetics and mechanism of the reaction of iron(III) with 6-methyl-2,4-heptanedione and 3,5-heptanedione

1990 ◽  
Vol 55 (8) ◽  
pp. 1984-1990 ◽  
Author(s):  
José M. Hernando ◽  
Olimpio Montero ◽  
Carlos Blanco
Keyword(s):  
Aqueous Solution ◽  
Metal Ion ◽  
Activation Parameters ◽  
Enol Form ◽  
Kinetics And Mechanism ◽  
Kinetic Constants ◽  
Steric Factors ◽  
Kinetics Of ◽  
Mechanism Of The Reaction

The kinetics of the reactions of iron(III) with 6-methyl-2,4-heptanedione and 3,5-heptanedione to form the corresponding monocomplexes have been studied spectrophotometrically in the range 5 °C to 16 °C at I 25 mol l-1 in aqueous solution. In the proposed mechanism for the two complexes, the enol form reacts with the metal ion by parallel acid-independent and inverse-acid paths. The kinetic constants for both pathways have been calculated at five temperatures. Activation parameters have also been calculated. The results are consistent with an associative activation for Fe(H2O)63+ and dissociative activation for Fe(H2O)5(OH)2+. The differences in the results for the complexes of heptanediones studied are interpreted in terms of steric factors.

Chemistry of the Diazeniumdiolates. 2. Kinetics and Mechanism of Dissociation to Nitric Oxide in Aqueous Solution

2001 ◽  
Vol 123 (23) ◽  
pp. 5473-5481 ◽  
Author(s):  
Keith M. Davies ◽  
David A. Wink ◽  
Joseph E. Saavedra ◽  
Larry K. Keefer
Keyword(s):  
Nitric Oxide ◽  
Aqueous Solution ◽  
Kinetics And Mechanism

Kinetics and mechanism of the decarboxylation of anthranilic acid in aqueous solution

1968 ◽  
Vol 72 (9) ◽  
pp. 3142-3148 ◽  
Author(s):  
Alfred V. Willi ◽  
Chong Min Won ◽  
Paul Vilk
Keyword(s):  
Aqueous Solution ◽  
Anthranilic Acid ◽  
Kinetics And Mechanism

The kinetics and mechanism of the acid-catalysed detritylation of nucleotides in non-aqueous solution

2009 ◽  
Vol 7 (1) ◽  
pp. 52-57 ◽  
Author(s):  
Mark A. Russell ◽  
Andrew P. Laws ◽  
John H. Atherton ◽  
Michael I. Page
Keyword(s):  
Aqueous Solution ◽  
Kinetics And Mechanism
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