Solute-solvent interactions in water-tert-butyl alcohol mixtures. III. ?G ?, ?H ?, and ?S ? for dissociation of aliphatic carboxylic acids in water-rich media

1974 ◽  
Vol 3 (5) ◽  
pp. 403-415 ◽  
Author(s):  
J-P. Morel ◽  
J. Fauve ◽  
L. Av�dikian ◽  
J. Juillard
Keyword(s):  
Carboxylic Acids ◽  
Butyl Alcohol ◽  
Solvent Interactions ◽  
Tert Butyl ◽  
Rich Media ◽  
Tert Butyl Alcohol ◽  
Alcohol Mixtures ◽  
Aliphatic Carboxylic Acids

Thermodynamic and Kinetic Investigation of the Solvent Effect on the Oxidation of [Co(en)2SCH2COO]+ with S2O82- In Water-Methanol and Water-tert-Butyl Alcohol Mixtures

1993 ◽  
Vol 58 (5) ◽  
pp. 1001-1006 ◽  
Author(s):  
Oľga Vollárová ◽  
Ján Benko
Keyword(s):  
Transfer Functions ◽  
Activation Parameters ◽  
Butyl Alcohol ◽  
Oxidation Of Co ◽  
Kinetics Of Oxidation ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
Alcohol Mixtures ◽  
Kinetics Of

The kinetics of oxidation of [Co(en)2SCH2COO]+ with S2O82- was studied in water-methanol and water-tert-butyl alcohol mixtures. Changes in the reaction activation parameters ∆H≠ and ∆S≠ with varying concentration of the co-solvent depend on the kind of the latter, which points to a significant role of salvation effects. The solvation effect on the reaction is discussed based on a comparison of the transfer functions ∆Ht0, ∆St0 and ∆Gt0 for the initial and transition states with the changes in the activation parameters accompanying changes in the CO-solvent concentration. The transfer enthalpies of the reactant were obtained from calorimetric measurements.

Positron annihilation in and compressibility of liquid water + tert-butyl alcohol mixtures

1997 ◽  
Vol 214 (1) ◽  
pp. 143-149 ◽  
Author(s):  
Andrzej Baranowski ◽  
Kazimierz Jerie ◽  
Jacek Gliński
Keyword(s):  
Positron Annihilation ◽  
Liquid Water ◽  
Butyl Alcohol ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
Alcohol Mixtures

Dissociation of the ammonium ion in water-urea and water-tert-butyl alcohol mixtures

Talanta ◽  
1976 ◽  
Vol 23 (10) ◽  
pp. 741-742 ◽  
Author(s):  
Yvon Pointud ◽  
Henri Gillet ◽  
Jean Juillard
Keyword(s):  
Butyl Alcohol ◽  
Ammonium Ion ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
Alcohol Mixtures
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