Linear free energy relationships and kinetics of ligand substitutions: Correlations of rate constants with overall stability constants of reactive intermediate species in the stepwise formation of pentacyanohydroxoferrate(III) from monohydroxoaminocarboxylato iron(III) complexes

1985 ◽  
Vol 10 (6) ◽  
pp. 220-223 ◽  
Author(s):  
Radhey M. Naik ◽  
Prem C. Nigam
Keyword(s):  
Free Energy ◽  
Rate Constants ◽  
Linear Free Energy Relationships ◽  
Reactive Intermediate ◽  
Intermediate Species ◽  
Linear Free Energy ◽  
Overall Stability ◽  
Energy Relationships ◽  
Kinetics Of ◽  
Stepwise Formation

Linear free energy relationships on rate constants for dechlorination by zero-valent iron

2002 ◽  
Vol 13 (6) ◽  
pp. 597-606 ◽  
Author(s):  
J. Chen ◽  
J. Pei ◽  
X. Quan ◽  
Y. Zhao ◽  
S. Chen ◽  
...  
Keyword(s):  
Free Energy ◽  
Rate Constants ◽  
Zero Valent Iron ◽  
Linear Free Energy Relationships ◽  
Linear Free Energy ◽  
Energy Relationships

Establishing linear-free-energy relationships for the quadricyclane-to-norbornadiene reaction

2020 ◽  
Vol 18 (11) ◽  
pp. 2113-2119 ◽  
Author(s):  
Mads Mansø ◽  
Anne Ugleholdt Petersen ◽  
Kasper Moth-Poulsen ◽  
Mogens Brøndsted Nielsen
Keyword(s):  
Free Energy ◽  
Linear Free Energy Relationship ◽  
Linear Free Energy Relationships ◽  
Linear Free Energy ◽  
Energy Relationships ◽  
Kinetics Of ◽  
Selection Of

The kinetics of the thermal quadricyclane-to-norbornadiene (QC-to-NBD) isomerization follows a linear-free-energy relationship when using Creary radical values for a selection of aryl/cyano disubstituted derivatives.

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