Additive Linear Free-Energy Relationships in Reaction Kinetics of Amino Groups with α,β-Unsaturated Compounds1,2

1966 ◽  
Vol 31 (9) ◽  
pp. 2888-2894 ◽  
Author(s):  
Mendel Friedman ◽  
Joseph S. Wall
2020 ◽  
Vol 18 (11) ◽  
pp. 2113-2119 ◽  
Author(s):  
Mads Mansø ◽  
Anne Ugleholdt Petersen ◽  
Kasper Moth-Poulsen ◽  
Mogens Brøndsted Nielsen

The kinetics of the thermal quadricyclane-to-norbornadiene (QC-to-NBD) isomerization follows a linear-free-energy relationship when using Creary radical values for a selection of aryl/cyano disubstituted derivatives.


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