Thermal desorption study of catalytic systems. 17. Reaction of carbon monoxide with water on the surface of skeletal copper

Author(s):  
V. N. Gel'man ◽  
A. M. Varlamova ◽  
V. S. Sobolevskii ◽  
E. Z. Golosman ◽  
V. I. Yakerson
1976 ◽  
Vol 55 (2) ◽  
pp. 389-402 ◽  
Author(s):  
Douglas M Collins ◽  
James B Lee ◽  
W.E Spicer

2020 ◽  
Vol 24 ◽  
Author(s):  
Yanlin Zong ◽  
Qiankun Li ◽  
Hongliang Mu ◽  
Zhongbao Jian

Abstract:: The copolymers of carbon monoxide (CO) and olefins, namely polyketones, are a family of widely used materi-als. In the catalytic preparation of these materials, palladium(II) catalysts represent the most successful catalytic systems. The production of both alternating and non-alternating polyketones has been achieved, with great difference in their physical properties. Herein, a variety of palladium(II) catalysts employed for the copolymerization of CO with various olefinic mon-omers such as ethylene, α-olefins, styrene and polar vinyl monomers are fully summarized. The influence of important fac-tors such as solvents and counterions on specific copolymerization, is also discussed. This review aims to enlighten the de-sign of new Pd catalysts with improved properties, as well as the development of new polyketone materials.


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