Rhodiom(III) complexes with O-alkyl-S-alkyl thiocarbonates as catalysts for the homogeneous hydrogenation of unsaturated compounds

1989 ◽  
Vol 38 (10) ◽  
pp. 2149-2151
Author(s):  
V. N. Maistrenko ◽  
I. A. Rusakov ◽  
S. O. Bondareva ◽  
Yu. I. Murinov ◽  
G. A. Tolstikov
Keyword(s):  
Homogeneous Hydrogenation ◽  
Unsaturated Compounds

Notizen: Homogene katalytische Hydrierung ungesättigter Verbindungen mit H2PtCl6 plus SnCl2 · 2 H2O in iso-Propanol.

1976 ◽  
Vol 31 (3) ◽  
pp. 387-392 ◽  
Author(s):  
Walter Strohmeier ◽  
Luise Weigelt
Keyword(s):  
Double Bond ◽  
Reaction Rates ◽  
Hydrogenation Rate ◽  
Homogeneous Hydrogenation ◽  
Mild Conditions ◽  
Unsaturated Compounds

A catalytical system for homogeneous hydrogenation of unsaturated compounds, operating under mild conditions can be prepared with H2PtCl6-SnCl2 · 2 H2O and the additives HBr and H2O in iso-propanol. Reaction rates up to 32 mMol · l-1 · min-1 were observed. After hydrogenation of one batch new substrate can be injected several times without noticeable desactivation of the system. Hydrogenation rate of 2-tr-cis-hexene is only 0,5 times less than of 1-hexene. Mesityloxide is selectively hydrogenated regarding the double bond.

ChemInform Abstract: Complexes of Rhodium(III) with O-Alkyl S-Alkyl Thiocarbonates as Catalysts in the Homogeneous Hydrogenation of Unsaturated Compounds.

ChemInform ◽  
1990 ◽  
Vol 21 (19) ◽  
Author(s):  
V. N. MAISTRENKO ◽  
I. A. RUSAKOV ◽  
S. O. BONDAREVA ◽  
YU. I. MURINOV ◽  
G. A. TOLSTIKOV
Keyword(s):  
Homogeneous Hydrogenation ◽  
Unsaturated Compounds
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